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Updated: Sep 12, 2025

Synthesis of a Thiol Building Block for the Crystallization of a Semiconducting Gyroidal Metal-sulfur Framework
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Published on: April 9, 2018

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铜单原子催化剂用于Thioether合成中的高效C─S合

Theodore A Gazis1, Shilpa Palit1, Luis A Cipriano1

  • 1Department of Chemistry, Materials, and Chemical Engineering "Giulio Natta", Politecnico di Milano, Piazza Leonardo da Vinci 32, Milano, 20133, Italy.

Angewandte Chemie (International ed. in English)
|August 6, 2025
PubMed
概括

研究人员开发了一种可回收的铜单原子催化剂,用于高效的碳硫键形成. 这一突破解决了合成用于制药和材料的乙烯的挑战,为传统方法提供了更绿色的替代方案.

关键词:
交叉合反应 交叉合反应C─S 债券形成密度函数理论密度函数理论精细化学合成 精细化学合成一个原子的催化剂.

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Sulfides are the sulfur analog of ethers, just as thiols are the sulfur analog of alcohol. Like ethers, sulfides also consist of two hydrocarbon groups bonded to the central sulfur atom. Depending upon the type of groups present, sulfides can be symmetrical or asymmetrical. Symmetrical sulfides can be prepared via an SN2 reaction between 2 equivalents of an alkyl halide and one equivalent of sodium sulfide.
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Introduction
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