解码阳光照射水中溶解有机物质的周期驱动光变:多维性质转移和分子网络重构
Kaiting Zhang1, Ruiqi Zheng1, Lihua Li1
1Fujian Key Laboratory of Coastal Pollution Prevention and Control, College of the Environment & Ecology, Xiamen University, Xiamen 361102, China.
Water research
|August 6, 2025
概括
从先进的氧化过程中产生的残留周期物 (PI) 改变了水中溶解有机物 (DOM) 的光变. PI加速DOM分解和释放,影响水中碳和循环.
科学领域:
- 环境化学环境化学
- 水生化学 水生化学
- 先进的氧化过程 先进的氧化过程
背景情况:
- 来自先进氧化过程 (AOPs) 的残留周期物 (PI) 是一种新出现的污染物.
- 对PI对溶解有机物 (DOM) 光变化的影响及其对水生碳循环的后续影响尚不清楚.
研究的目的:
- 为了研究残留周期酸盐在太阳辐射下对DOM光变的多维影响.
- 阐明PI改变DOM结构,反应性和循环的机制.
主要方法:
- 实时光物理,电化学和光化学跟踪.
- 使用FT-ICR MS与配对的质距离网络的分子反应组学.
- 可解释机器学习 (XGBoost与SHAP分析).
主要成果:
- PI残留物诱导了芳香结构的碎片化,降低了表面分子量,并增加了DOM氧化还原能力.
- 太阳能/PI系统增强了光化学反应性,增加了3DOM*和基 (•OH) 的量子产量.
- PI促进了CN键裂解和小分子的聚合,与自然光衰老形成鲜明对比,其中起了关键作用.
结论:
- 剩余周期性物质显著重编程DOM光变,转向以N为中心的过程.
- 这种转化加速了溶解的有机的产生,增加了消毒副产品的风险.
- 这些发现重新定义了在水生环境中人为氧化应激下DOM转化机制.
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