B/N/P协同系统用于具有热稳定性和优良物理性能的多功能阻燃棉织物
Gongze Ji1, Fengying Lan1, Chen Chen1
1College of Chemistry and Chemical Engineering, Qingdao University, Qingdao 266071, PR China.
International journal of biological macromolecules
|August 6, 2025
概括
一种新的阻燃剂,PNBAPP,已开发用于棉织物,显著提高耐火性和耐用性. 经过修改的织物显示了改善的安全性,在多次洗后持续的性能.
科学领域:
- 材料科学 材料科学 材料科学
- 织品化学 织品化学
- 聚合物化学 聚合物化学
背景情况:
- 棉织物固有的易燃性限制了其在苛刻的应用中使用.
- 开发有效的阻燃处理对于提高棉花的安全性和多功能性至关重要.
研究的目的:
- 为棉织物合成和评估一种多元素协同阻燃剂 (PNBAPP).
- 评估PNBAPP修饰棉花的阻燃效果,耐用性和其他特性.
主要方法:
- 通过结合 (B), (N) 和 (P) 元素来开发PNBAPP.
- 使用限制氧指数 (LOI),垂直可燃性测试,形热量测量 (CCT) 和热重力测量分析 (TG) 的评估.
- 通过50个洗周期评估耐用性,并分析物理,热和抗菌性质.
主要成果:
- PNBAPP显著地将棉花的LOI从18%提高到42.1%,并减少了可燃性测试中的损伤长度.
- 经过50次洗后,火焰阻燃性保持在25.6%的LOI.
- CCT和TG分析证实了减少的热释放和增加的炭含量 (在800°C时从16.58%增加到33.45%),表明增强的热稳定性和催化碳化.
结论:
- PNBAPP表现出优异的阻燃性能和棉织物的热稳定性.
- 这种修改赋予了持久的耐火性,而不会损害面料的基本特性,如白度和物理完整性.
- 开发的阻燃剂为提高棉花材料的安全性提供了一个有希望的解决方案.
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