从挖掘岩石中释放潜在有害元素,并在干湿周期下改变表面
Yuto Yoshida1, Hirofumi Sakanakura2, Masahiko Katoh3
1Department of Agricultural Chemistry, Graduate School of Agriculture, Meiji University, 1-1-1, Higashimita, Tama, Kawasaki, Kanagawa 214-8571, Japan; Material Cycles Division, National Institute for Environmental Studies, 16-2, Onogawa, Tsukuba, Ibaraki 305-8506, Japan.
The Science of the total environment
|August 7, 2025
概括
干湿循环改变了挖掘的岩石,影响了潜在有害元素 (PHE) 的释放. 化氧化驱动PHE释放,而铁沉减少和,但不减少或,影响环境风险评估.
科学领域:
- 环境科学 环境科学
- 地质化学 地质化学
- 建筑材料科学 建筑材料科学
背景情况:
- 在建筑中挖掘的岩石可能含有潜在有害元素 (PHEs).
- 再利用这些岩石需要了解PHE释放机制,特别是在干湿周期下.
- 堤防容易受到干湿周期的环境变化的影响.
研究的目的:
- 调查挖掘岩石表面变化与干湿周期下的PHE释放之间的关系.
- 为了识别导致PHE物种释放变化的特定变化.
- 评估与再利用挖掘岩石相关的环境风险.
主要方法:
- 在挖掘岩石上模拟干湿周期.
- 监测表面的变化:金氧化,细粒化,石灰岩和石膏的形成.
- 量化PHE释放 (,,,,) 并确定它们的化学形式.
主要成果:
- 铁矿氧化,细粒化和石膏形成在第一个月达到最高水平.
- 连续的干湿循环促进了进一步的矿氧化和细粒化,但石膏形成停止了.
- ,和由于正在进行的矿氧化和颗粒化而释放;铁沉减少了和,但没有或.
结论:
- 矿氧化和细粒化是从挖掘岩石中释放PHE的主要驱动因素.
- 表面变化显著影响PHEs的移动性和物种化.
- 对重复使用的挖掘岩石的环境风险评估必须考虑由表面变化影响的PHE释放.
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