可变温度X射线散射揭示了含有的电子受体的高效有机光伏的溶液聚合结构和处理弹性
Mengyuan Gao1,2, Kai Zhang1, Wenchao Zhao3
1School of Materials Science & Engineering, State Key Laboratory of Advanced Materials for Intelligent Sensing, Tianjin Key Laboratory of Molecular Optoelectronic Sciences, Key Laboratory of Organic Integrated Circuits, Ministry of Education, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin University, Tianjin, 300350, China.
带有的BO-4I接受器的高效聚合物光伏显示出稳定的溶液聚合,从而提高了灵活电源的加工弹性和长期设备稳定性.
科学领域:
- 材料科学 材料科学 材料科学
- 可再生能源可再生能源是可再生能源.
- 聚合物化学 聚合物化学
背景情况:
- 聚合物光伏 (PPV) 提供低成本,灵活的电力解决方案.
- 设备的性能严重依赖于捐赠物和接受物材料的混合物形态和聚合结构.
- 了解解决方案聚合是控制薄膜形态和设备效率的关键.
研究的目的:
- 为了研究聚合物光伏的溶液聚合行为和处理弹性,使用含的电子接受器BO-4I.
- 为了比较BO-4I与其化模拟物的聚合特性.
- 建立结构属性关系,将溶液聚合与膜形态和设备性能联系起来.
主要方法:
- 使用可变温度小角度X射线散射 (SAXS) 和中子散射 (SANS) 来探测溶液聚合.
- 分析了片形态与设备性能特征结合.
- 使用含 (BO-4I) 和含的电子受体进行了比较研究.
主要成果:
- 在常见的有机溶剂中,BO-4I表现出优异的溶液处理稳定性.
- 混合物聚合中的温度诱导的变化对薄膜形态和设备性能产生了重大影响.
- 在BO-4I系统中稳定的解决方案聚合结构导致了增强的处理弹性和长期设备稳定性.
- 在溶液中确定了27 ± 3nm的关键聚合物聚合物长度,以获得最佳的有机光伏效率.
结论:
- -4I的稳定溶液聚合有助于加工弹性和改善聚合物光伏的长期稳定性.
- 从溶液到膜的结构继承对于高性能设备至关重要.
- 控制溶液中的聚合物聚合物长度是设计高效和稳定的聚合物光伏系统的关键策略.
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