煤灰通过微波路线无形化,作为潜在的吸附剂,用于在水中去除污染物
Pietro Serraglio Figueiredo1, Sérgio Luiz Jahn1, Tito Crissien2
1Research Group On Adsorptive and Catalytic Process Engineering (ENGEPAC), Federal University of Santa Maria, Av. Roraima, 1000-7, Santa Maria, 97105-900, Brazil.
Environmental science and pollution research international
|August 9, 2025
概括
这项研究提出了一种新方法,将煤灰转化为有效的吸附剂,用于从水中去除水晶紫色染料. 微波辅助的性聚变过程显著增强了灰用于废水处理的特性.
科学领域:
- 材料科学 材料科学 材料科学
- 环境化学环境化学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 煤灰是一种重要的工业副产品,具有环境应用的潜力.
- 传统的废水处理方法经常面临效率和成本方面的挑战.
- 从废物中开发新型吸附剂对于可持续发展至关重要.
研究的目的:
- 开发一种新的,快速的煤灰形态化的方法.
- 为了研究微波形态化灰 (MWAA) 作为晶体紫色 (CV) 染料去除吸附剂的有效性.
- 优化吸附条件并评估开发的吸附剂的可重复使用性.
主要方法:
- 煤灰通过微波辅助性聚变 (1000 W,3 分钟) 使用固体 NaOH 进行无形化.
- 无形煤灰 (MWAA) 的孔状性质的表征.
- 使用中央复合可旋设计 (CCRD) 优化吸附条件 (pH,吸附剂剂量).
- 吸附实验以确定吸附容量并研究吸附热力学和动力学.
主要成果:
- 微波辅助性聚变显著改善了表面积 (1.23到66.28米2g-1) 和孔隙体积 (0.0045到0.1934厘米3g-1).
- 最佳吸附条件被确定为pH 9和0.7g L-1吸附剂剂量.
- 最大吸附能力达到142毫克g-1,具有自发,外热和有利的吸附动力学.
- 在四个循环中,MWAA表现出良好的可重复使用性.
结论:
- 微波辅助性聚变是一种有效和快速的方法,可以从煤灰中产生先进的吸附剂.
- 作为一个具有成本效益和可持续的吸附剂,MWAA具有显著的潜力,用于从废水中去除水晶紫色染料.
- 这种方法为煤灰利用和工业废水处理提供了一个有希望的解决方案.
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