设计功能性viologen盐具有巨大的离子导电性通过 counterion 组成和链条长度:在哪里是极限?
Seonghyeok L Cox1, Si L Chen1, Jakob Smith1
1Department of Chemistry and Biochemistry, University of Nevada Las Vegas, 4505 S. Maryland Parkway, Box 454003, Las Vegas, NV 89154, USA.
概括
五种新型的二离子液 (DCIL) 盐与延长的生物核显示出高导电性,接近商业电解质. 这些材料为有机电子应用提供了有前途的性能.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 有机化学 有机化学
背景情况:
- 离子液体 (ILs) 是具有调节性质的多功能材料.
- 与单离子离子液相比,二离子离子液 (DCIL) 具有独特的特性.
- 基于viologen的材料以其氧化还原活性和色合性质而闻名.
研究的目的:
- 合成和表征基于新型延伸维奥基因的DCILs.
- 为了研究氧乙烯链长度和反离子对DCIL特性的影响.
- 评估这些新型DCIL的导电性和介电反应,以了解其潜在的应用.
主要方法:
- 合成了五种具有不同氧乙烯链长度 (n=3,7) 和反离子 (FSI,TFSI,ONf) 的新型DCIL盐.
- 使用技术来确定玻璃过渡温度 (Tg) 和结构性质的表征.
- 在有机溶剂中测量介电反应和离子导电性.
主要成果:
- 所有合成的DCIL都是无形的,由于灵活的氧乙烯链,其玻璃过渡温度接近或低于零.
- 在有机溶剂中,DCILs表现出染色体反应.
- 观察到高介电反应和导电性 (高达10^-0.5 S·cm^-1),特别是在FSI反离子.
结论:
- 开发的延长型紫外线DCILs在有机介质中表现出极好的导电性,与商业电解质相当.
- 氧乙烯链的塑化作用有助于有利的热性能.
- 这些DCIL代表了一类新的高性能离子液体,用于电化学应用.
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