相关实验视频
Updated: Sep 11, 2025

06:58
Zinc-Sponge Battery Electrodes that Suppress Dendrites
Published on: September 29, 2020
4.4K
泰吉灵感的协同吸引-排斥电静电相互作用使耐用高实际容量的水性-电池实现双电极稳定
Qilong Wu1, Rong Tang1, Peiyao Wang1
1State Key Laboratory of Physical Chemistry of Solid Surfaces, State-Province Joint Engineering Laboratory of Power Source Technology for New Energy Vehicle, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005, P.R. China.
Angewandte Chemie (International ed. in English)
|August 11, 2025
概括
一种新的双电极策略通过管理聚胺相互作用来稳定水性- (Zn-Br2) 电池. 这种方法提高了电网规模储能量的安全性和耐用性,实现了高容量和超过20,000个循环.
科学领域:
- 电化学 电化学 电化学
- 材料科学 材料科学 材料科学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 水性- (Zn-Br2) 电池提供安全和成本效益的电网规模的能源存储.
- 聚胺溶解和穿极限 Zn-Br 电池性能和寿命.
- 聚化物对阳极的腐蚀进一步降低了电池的稳定性.
研究的目的:
- 为耐用,大面积容量的Zn-Br电池开发双电极稳定策略.
- 在阴极和阳极上协同调节界面化学.
- 为了克服聚化物穿和阳极腐蚀的局限性.
主要方法:
- 实施了以太极为灵感的双电极稳定策略.
- 使用的聚二甲基化物 (PDDA) 用于阴极聚化物结合.
- 在阳极上构建了莲花叶生物模拟互相,用于排斥.
- 采用理论计算和现场光谱进行分析.
主要成果:
- 使用PDDA在阴极上实现了聚化物强的静电结合.
- 创建了一个疏水和电负阳极接相,以排斥多化物.
- 有效地抑制了聚化物穿和腐蚀.
- 证明了 5.5 mAh cm-2 的高面积容量.
- 实现了超过20,000个循环的特殊循环稳定性.
结论:
- 双接口工程对于推进实际Zn-Br电池技术至关重要.
- 开发的战略使耐用,高性能水性Zn-Br电池成为可能.
- 这种方法为电网规模的储能应用提供了一个有前途的解决方案.
相关概念视频
Standard Electrode Potentials
45.0K
On comparing the reactivity of silver and lead, it is observed that the two ionic species, Ag+ (aq) and Pb2+ (aq), show a difference in their redox reactivity towards copper: the silver ion undergoes spontaneous reduction, while the lead ion does not. This relative redox activity can be easily quantified in electrochemical cells by a property called cell potential. This property is commonly known as cell voltage in electrochemistry, and it is a measure of the energy which accompanies the charge...
45.0K
DC Battery
874
A conductor needs to be a component of a path that creates a closed loop or full circuit to have a continuous current flowing through it. A current starts to flow if an electric field is created inside an isolated conductor that is not part of a full circuit. The conductor quickly develops a net positive charge at one end and a net negative charge at the other. These charges generate an electric field opposite the direction of the applied electric field, which reduces the current. Eventually,...
874
Induced Electric Dipoles
4.4K
A permanent electric dipole orients itself along an external electric field. This rotation can be quantified by defining the potential energy because the external torque does work in rotating it. Then, the potential energy is minimum at the parallel configuration and maximum at the antiparallel configuration. While the former is a stable equilibrium, the latter is an unstable equilibrium.
Since the absolute value of potential energy holds no physical meaning, its zero value can be chosen as per...
Since the absolute value of potential energy holds no physical meaning, its zero value can be chosen as per...
4.4K
Electrolysis
27.3K
In a galvanic cell, the electrical work is done by a redox system on its surroundings as electrons produced by the spontaneous redox reactions are transferred through an external circuit. Alternatively, an external circuit does work on a redox system by imposing a voltage sufficient to drive an otherwise nonspontaneous reaction in a process known as electrolysis. For instance, recharging a battery involves the use of an external power source to drive the spontaneous (discharge) cell reaction in...
27.3K
Voltaic/Galvanic Cells
58.4K
Spontaneous Chemical Reactions
Spontaneous redox reactions occur abundantly in nature. The chemical reaction occurring in a disposable AA battery powering our remote controls is one such example of a spontaneous redox reaction. Another example is the immersion of coiled copper wire into an aqueous silver nitrate solution. The reaction shows a gradual, visually impressive color change from colorless to bright blue and the formation of a grey precipitate on the copper wire. In this experiment,...
Spontaneous redox reactions occur abundantly in nature. The chemical reaction occurring in a disposable AA battery powering our remote controls is one such example of a spontaneous redox reaction. Another example is the immersion of coiled copper wire into an aqueous silver nitrate solution. The reaction shows a gradual, visually impressive color change from colorless to bright blue and the formation of a grey precipitate on the copper wire. In this experiment,...
58.4K
Batteries and Fuel Cells
28.0K
A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
28.0K

