结构复杂性是由液态-液态晶相分离的涂料驱动的
Christopher A Browne1, Yuma Morimitsu1, Na Kyung Kim1
1Department of Chemical and Biomolecular Engineering, University of Pennsylvania, USA. cosuji@seas.upenn.edu.
Soft matter
|August 12, 2025
概括
液-液晶相分离 (LLCPS) 创造了多样化的滴状结构. 溶剂膨胀和冷却路径极大地影响了从凝中形成复杂的丝状网络.
科学领域:
- 材料科学 材料科学 材料科学
- 软物质物理学 软物质物理学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 复杂流体中的相位分离可以产生具有内部液晶秩序的液滴.
- 滴滴几何学受内部液晶相位相的弹性影响,形成像细丝和状体这样的结构.
- 之前的研究表明,丝状网络是通过缓慢冷却的液态液晶相分离 (LLCPS) 产生的.
研究的目的:
- 调查中质素,溶剂和度如何影响LLCPS形成的网络结构.
- 阐明溶剂膨胀和相分离途径在网络形态学上的作用.
- 了解液晶系统中形成网络结构所需的条件.
主要方法:
- 利用X射线散射来分析质凝结物的结构.
- 在相隔系统中系统地变化中原体,溶剂和度.
- 在受控冷却条件下观察到滴滴和网络形成.
主要成果:
- 溶剂膨胀的粘性层降低了曲模量,导致更复杂的网络几何形状.
- 较高的涂层胀与增加的几何复杂性相关,需要更大的层曲.
- 导线和网络的形成取决于路径,只有当形相从同位素相直接形成时才会发生.
结论:
- 溶剂和度的选择显著影响LLCPS形成的液滴的结构多样性.
- 溶剂引起的材料特性变化 (例如,曲模量) 是控制网络形态的关键.
- 路径依赖性,特别是从同otropic 阶段直接形成 smectic 阶段,对于网络组装至关重要.
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