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原子精确的奇拉PtAg4纳米集群的一合成

Yujie Zhang1, Hongli Jia2, Bingzheng Yan1

  • 1College of Energy Materials and Chemistry, Inner Mongolia University, Hohhot 010021, China. shen@imu.edu.cn.

Chemical communications (Cambridge, England)
|August 12, 2025
PubMed
概括

研究人员合成了一种新型的性双金属银复合体,[PtAg4Cl(BDPP) 4H]2+. 这种具有独特结构和光学特性的复合体,使用性联体2,4-bis(diphenylphosphino) pentane (BDPP) 进行了表征.

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Chirality at Nitrogen, Phosphorus, and Sulfur02:30

Chirality at Nitrogen, Phosphorus, and Sulfur

Chirality is most prevalent in carbon-based tetrahedral compounds, but this important facet of molecular symmetry extends to sp3-hybridized nitrogen, phosphorus and sulfur centers, including trivalent molecules with lone pairs. Here, the lone pair behaves as a functional group in addition to the other three substituents to form an analogous tetrahedral center that can be chiral.
A consequence of chirality is the need for enantiomeric resolution. While this is theoretically possible for all...
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