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X-ray Crystallography02:18

X-ray Crystallography

24.2K
The size of the unit cell and the arrangement of atoms in a crystal may be determined from measurements of the diffraction of X-rays by the crystal, termed X-ray crystallography.
Diffraction
Diffraction is the change in the direction of travel experienced by an electromagnetic wave when it encounters a physical barrier whose dimensions are comparable to those of the wavelength of the light. X-rays are electromagnetic radiation with wavelengths about as long as the distance between neighboring...
24.2K
X-ray Diffraction of Biological Samples01:10

X-ray Diffraction of Biological Samples

4.0K
X-ray diffraction or XRD is an analytical tool that utilizes X-rays to study ordered structures such as crystalline organic and inorganic samples, polycrystalline materials, proteins, carbohydrates, and drugs.
According to Bragg's law, when X-rays strike the sample positioned on a stage, the rays are  scattered by the electron clouds around the sample atoms. The  X-ray diffraction or scattering is caused by constructive interference of the X-ray waves that reflect off the internal...
4.0K
Absorption of Radiation01:05

Absorption of Radiation

820
The rate of heat transfer by emitted radiation is described by the Stefan-Boltzmann law of radiation:
820
¹H NMR: Interpreting Distorted and Overlapping Signals01:02

¹H NMR: Interpreting Distorted and Overlapping Signals

1.1K
Spin systems where the difference in chemical shifts of the coupled nuclei is greater than ten times J are called first-order spin systems. These nuclei are weakly coupled, and their chemical shifts and coupling constant can generally be estimated from the well-separated signals in the spectrum.
As Δν decreases and the signals move closer, the doublets appear increasingly distorted. The intensities of the inner lines increase at the cost of those of the outer lines as the signals are...
1.1K
Influence of Earth's Curvature and Atmospheric Refraction on Leveling01:26

Influence of Earth's Curvature and Atmospheric Refraction on Leveling

272
During leveling, the Earth's curvature and atmospheric refraction introduce deviations in the line of sight from a true horizontal reference. When the line of sight is leveled, it remains perpendicular to the plumb line only at a single point. Beyond this, it deviates due to the Earth’s curvature, represented by the correction C. For a sight distance D, the deviation can be derived using the relationship:This relationship shows that the deviation increases quadratically with distance.
272

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Updated: Sep 11, 2025

Measurement of Particle Size Distribution in Turbid Solutions by Dynamic Light Scattering Microscopy
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实用放射学中的二次衍射效应:分析的非对称结果.

Eric L Shirley

    Journal of the Optical Society of America. A, Optics, image science, and vision
    |August 12, 2025
    PubMed
    概括

    本研究介绍了光学放射测量中二次衍射效应的公式,有助于提高测量精度. 这些发现有助于简化衍射校正,以提高科学仪器的精度.

    科学领域:

    • 光学和光子学 在光学和光子学.
    • 计量学 计量学 计量学

    背景情况:

    • 光学放射测量对于各种科学和工业应用至关重要.
    • 衍射效应可以在这些测量中引入重大误差.
    • 准确的衍射校正对于可靠的数据至关重要.

    研究的目的:

    • 介绍二次衍射效应的领先项的公式.
    • 将这些公式与数值计算结果进行比较.
    • 为改善光学测量中的衍射校正提供基础.

    主要方法:

    • 对二次衍射的分析公式的推导.
    • 推导式与数字模拟结果的比较.
    • 对导致衍射误差的领先项进行分析.

    主要成果:

    • 成功地获得了二次衍射效应的公式.
    • 展示的公式显示了与数值计算的良好一致.
    • 确定了导致衍射诱导的辐射测量误差的关键术语.

    结论:

    • 衍生的公式为更准确的衍射校正提供了一条途径.
    • 促进了光学放射测量测量准确性的简化改进.

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  • 未来研究的潜力包括将这些纠正扩展到更高的订单.