源头的垂直分布和HONO在中国北方平原的大气影响
Huiying Xuan1,2, Chaofan Lian3, Pengkun Ma4
1State Key Laboratory of Regional Environment and Sustainability, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China.
高海拔的酸 (HONO) 化学是很少理解的. 这项研究揭示了高层热带层中独特的HONO来源和下沉点,改善了空气质量模型和臭氧预测.
科学领域:
- 大气化学 大气化学
- 空气质量建模空气质量模型
- 热带球过程 热带球过程
背景情况:
- 酸 (HONO) 是基基 (OH) 的关键前体,影响热层空气质量.
- 对于高海拔HONO来源和大气影响的了解有限.
研究的目的:
- 为了研究HONO化学在热带层的垂直分布.
- 通过结合额外的HONO源来增强社区多层次空气质量 (CMAQ) 模型.
- 改进臭氧和二次颗粒物的模拟.
主要方法:
- 使用了社区多层次空气质量 (CMAQ) 模型.
- 将五个新的HONO源纳入模型.
- 分析了HONO在不同大气层中的度,来源和沉降.
主要成果:
- 修订后的CMAQ模型准确地复制了观察到的HONO度.
- 表面HONO主要来源于NO2异质反应,其中扩散,干沉积和光解作为沉积点.
- 上空HONO来源包括NO + OH反应,NO2在气溶上的异质反应,以及垂直扩散,光解和向导作为下沉点.
结论:
- 截然不同的HONO源和下水槽在热带层内的不同高度具有特征.
- 了解垂直HONO分布对于准确的空气质量建模至关重要.
- 这项研究增强了对臭氧和二次颗粒物的模拟.
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