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相关概念视频

Inductively Coupled Plasma Atomic Emission Spectroscopy: Instrumentation01:26

Inductively Coupled Plasma Atomic Emission Spectroscopy: Instrumentation

296
Inductively coupled plasma (ICP) is the common plasma source used in atomic emission spectroscopy (AES), a technique that detects and analyzes various elements in a sample. This method is often called inductively coupled plasma atomic emission spectroscopy (ICP-AES).
There are three main types of inductively coupled plasma atomic emission spectroscopy  (ICP-AES) instruments: sequential, simultaneous multichannel, and Fourier transform instruments, with the latter being less commonly used....
296
Raman Spectroscopy: Overview01:20

Raman Spectroscopy: Overview

600
The underlying principle of Raman spectroscopy is based on the interaction between light and matter, specifically molecules' inelastic scattering of photons. When a monochromatic beam of light, typically from a laser source, interacts with a sample, most scattered light has the same frequency as the incident light. This is known as Rayleigh scattering.
However, a small fraction of the scattered light exhibits a frequency shift due to the exchange of energy between the incident photons and...
600
¹³C NMR: Distortionless Enhancement by Polarization Transfer (DEPT)01:20

¹³C NMR: Distortionless Enhancement by Polarization Transfer (DEPT)

1.2K
When proton-coupled carbon-13 spectra are simplified by a broadband proton decoupling technique, structural information about the coupled protons is lost. Distortionless enhancement by polarization transfer (DEPT) is a technique that provides information on the number of hydrogens attached to each carbon in a molecule. While the DEPT experiment utilizes complex pulse sequences, the pulse delay and flip angle are specifically manipulated. The resulting signals have different phases depending on...
1.2K
Atomic Emission Spectroscopy: Overview01:20

Atomic Emission Spectroscopy: Overview

2.5K
Atomic emission spectroscopy (AES) is an analytical technique used to determine the elemental composition of a sample by analyzing the light emitted from excited atoms. In AES, atoms in a sample are excited to higher energy levels by thermal energy from high-temperature sources, such as plasma, arcs, or sparks. When these excited atoms return to lower energy states, they emit light at specific wavelengths characteristic of each element. The resulting atomic emission spectrum, which consists of...
2.5K
IR Spectrum Peak Splitting: Symmetric vs Asymmetric Vibrations01:08

IR Spectrum Peak Splitting: Symmetric vs Asymmetric Vibrations

1.2K
Identical bonds within a polyatomic group can stretch symmetrically (in-phase) or asymmetrically (out-of-phase). Similar to hydrogen bonding, these vibrations also influence the shape of the IR peak. Generally, asymmetric stretching frequencies are higher than symmetric stretching frequencies. For example, primary amines exhibit two distinct IR peaks between 3300–3500 cm−1 corresponding to the symmetric and asymmetric N-H stretching, while secondary amines exhibit a single...
1.2K
¹³C NMR: ¹H–¹³C Decoupling01:04

¹³C NMR: ¹H–¹³C Decoupling

1.2K
The probability of having two carbon-13 atoms next to each other is negligible because of the low natural abundance of carbon-13. Consequently, peak splitting due to carbon-carbon spin-spin coupling is not observed in spectra. However, protons up to three sigma bonds away split the carbon signal according to the n+1 rule, resulting in complicated spectra.
A broadband decoupling technique is used to simplify these complex, sometimes overlapping, signals. Broadband decoupling relies on a...
1.2K

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相关实验视频

Updated: Sep 11, 2025

Synthesis and Operation of Fluorescent-core Microcavities for Refractometric Sensing
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基线无波长调制光谱基于塞普斯特拉分析.

Zhenhai Wang, Ning Zhu, Weitian Wang

    Optics express
    |August 13, 2025
    PubMed
    概括

    一种新的波长调制光谱 (WMS) m-FID技术提供了准确的,没有基线的测量. 这种基于塞普斯特拉分析的方法显著加快了燃烧分析.

    科学领域:

    • 频谱学是一种光谱学.
    • 燃烧诊断仪器的使用
    • 物理化学 物理化学

    背景情况:

    • 准确地在现场监测燃烧气体对于理解和控制燃烧过程至关重要.
    • 波长调制光谱 (WMS) 和直接吸收光谱 (DAS) 等现有技术在准确性,速度或基线稳定性方面存在局限性.
    • 开发新的光谱方法对于推进燃烧研究和应用至关重要.

    研究的目的:

    • 引入和验证一种新的波长调制光谱 - 分子自由诱导衰变 (WMS m-FID) 技术.
    • 证明该技术在静态气体电池和高温火焰中进行定量,准确和无基线测量的能力.
    • 评估WMS m-FID方法的计算效率和稳定性,与既有方法相比.

    主要方法:

    • 开发一种WMS m-FID技术,将cepstral分析与WMS和修改的时间域m-FID信号相结合.
    • 对于WMS m-FID技术的理论框架和安装例行调查.
    • 验证实验使用静态CO气体电池和预混合CH4 /空气层状火焰在平火烧炉上的验证实验.
    • 与直接吸收光谱 (DAS) 和WMS-2f/1f技术进行比较.

    主要成果:

    • 在静态CO测量中,WMS m-FID技术实现了安装误差<1.0%和0.17%的相对不确定性.

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  • 在CH4/空气火焰中,该技术产生了温度 (1763K) 和H2O度 (16.58%) 的低不确定性 (30K和0.65%,分别).
  • 通过WMS m-FID方法,计算效率提高了22倍,并实现了完全没有基线的CO测量.
  • 结论:

    • 拟议的WMS m-FID技术提供了定量,准确和没有基线的测量.
    • 该技术在静态和动态燃烧环境中具有强大可靠性.
    • WMS m-FID在计算效率上提供了显著的改进,使其成为现场燃烧监控的一个有前途的工具.