在放松器或铁电器中出现的拓极化纹理
Maksim Eremenko1,2,3, Victor Krayzman4,5, Semen Gorfman6
1Materials Measurement Science Division, National Institute of Standards and Technology, Gaithersburg, MD, USA. eremenkom@ornl.gov.
Nature communications
|August 13, 2025
概括
放松的铁电器表现出复杂的极地纹理,揭示了与半斯基尔米翁 (梅龙) 旋的自我组织的旋转极化. 这些由化学混乱驱动的拓结构为先进的介电和铁电材料提供了新的途径.
科学领域:
- 材料科学 材料科学 材料科学
- 凝聚物质物理学 凝聚物质物理学
- 固态化学 固态化学
背景情况:
- 放松铁电对于执行器和传感器至关重要.
- 它们的宽带介电反应的起源与极性异质有关.
- 了解这些结构是优化材料性能的关键.
研究的目的:
- 为了研究PbMg1 / 3Nb2 / 3O3-PbTiO3放松铁电器中的3D中等尺度极化结构.
- 挑战现有的极地纳米区域模型.
- 阐明化学乱在稳定极化纹理中的作用.
主要方法:
- 使用统一的多式联运结构改进框架.
- 同时安装X射线和中子总散射数据.
- 集成的X射线吸收光谱和扩散散射分析.
主要成果:
- 重建的3D大尺度极化地图显示了自我组织的旋转极化纹理.
- 在这些纹理中识别了半斯基尔米翁 (梅龙) .
- 相关的芯与局部电荷和应变梯度来自组成异质.
结论:
- 观察到的纹理挑战了独立极性纳米区域的模型.
- 化学乱,通过脱极化和应变场,稳定了拓纹理.
- 这些发现为设计新型介电和铁电功能提供了途径.
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