高的AlxCoCrFeNi合金在热电接口上实现了同时的电力和机械强度
Xiaoxia Zou1,2, Wangjie Zhou1,2, Xinxin Li1,2
1Engineering Research Center of Complex Track Processing Technology & Equipment, Ministry of Education, Xiangtan University, Xiangtan 411105, China.
Materials (Basel, Switzerland)
|August 14, 2025
概括
高合金 (HEA) 为热电发电机组创建稳定的接口. 这些AlxCoCrFeNi屏障层在高温应用中提高了电气和机械性能.
科学领域:
- 材料科学 材料科学 材料科学
- 能源转换 能源转换
- 纳米技术纳米技术
背景情况:
- 热电发电机 (TEG) 的效率和可靠性取决于高温接口.
- 开发强大的接口材料对于先进的TEG应用至关重要.
研究的目的:
- 研究AlxCoCrFeNi高合金 (HEA) 作为将铜 (Cu-W) 电极与p型 skutterudite (p-SKD) 热电材料结合的屏障层.
- 在高温操作下评估HEA/p-SKD接口的电气和机械稳定性.
主要方法:
- 在Cu-W电极和p-SKD材料之间制造HEA屏障层.
- 界面反应层的表征,电阻力和剪切强度.
- 在773K和热循环 (623-773K) 进行长期老化试验以评估稳定性.
主要成果:
- 在HEA/p-SKD接口形成的稳定,无缺陷的 (Fe,Ni,Co,Cr) Sb反应层 (~2.5μm).
- 达到0.26 μΩ·cm2的初始界面电阻低,在773 K的16天后增加到仅7.15 μΩ·cm2.
- 证明了88MPa的高初始切削强度,在老化后保持74MPa (16%降解),在100个热循环后保持29MPa.
结论:
- AlxCoCrFeNi HEAs是热电发电机的有效接口材料.
- 拟议的接口表现出优异的化学结合,低电阻,在恶劣的环境中优异的热力学稳定性.
- 这些发现可以同时优化高温TEG的电气和机械性能.
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