能量共晶的最常见成分的有毒作用
Xinying Peng1,2, Cunzhi Li1,2, Huan Li1,2
1Toxicology Research Center, Institute for Hygiene of Ordnance Industry, NO. 12 Zhangbadong Road, Yanta District, Xi'an 710065, China.
Molecules (Basel, Switzerland)
|August 14, 2025
概括
六二氧化 (CL-20) 共同晶体提高了爆炸性能,但引发了安全问题. 本次审查重点关注它们的毒性和环境风险,旨在寻找更安全的能源材料.
科学领域:
- 材料科学 材料科学 材料科学
- 化学 化学 化学
- 毒理学 毒理学 毒理学
背景情况:
- 六化 (CL-20) 提供高能量密度,但由于敏感性而带来安全风险.
- 研究CL-20共晶体是为了平衡能量输出和安全.
- 对CL-20共晶体的毒性和环境影响是关键问题.
研究的目的:
- 系统地审查CL-20共晶能量材料的最新进展.
- 强调CL-20共晶元件的毒性概况和机械洞察力.
- 为开发更安全的能源材料提供基础.
主要方法:
- 关于CL-20共晶合成和表征的近期进展的文献综述.
- 对CL-20共晶的毒性数据和环境风险评估的分析.
- 对优化CL-20共晶性质的计算设计技术的研究.
主要成果:
- 新的合成方法和计算设计策略已经推进了CL-20共晶的发展.
- 重点关注的是了解和减轻CL-20及其共晶形式的毒性.
- 对组件相互作用的机制洞察力对于安全评估至关重要.
结论:
- 开发更安全的基于CL-20的能量材料需要对其毒性和环境影响有充分的了解.
- 制造业和工业应用的可持续进步取决于解决这些安全问题.
- 对毒性概况和机械洞察力的进一步研究对于下一代能量材料至关重要.
相关概念视频
Toxic Reactions: Overview
1.2K
When toxic substances penetrate the human body, they disseminate to various tissues, undergoing metabolic changes. This process yields reactive metabolites that may covalently bind with specific target molecules, resulting in toxicity.
Toxicity falls into two primary categories: local and systemic.
Local toxicity appears at the exposure site, such as protein denaturation caused by caustic substances.
In contrast, systemic toxicity requires the toxic agent's absorption and distribution,...
Toxicity falls into two primary categories: local and systemic.
Local toxicity appears at the exposure site, such as protein denaturation caused by caustic substances.
In contrast, systemic toxicity requires the toxic agent's absorption and distribution,...
1.2K
Crystal Field Theory - Octahedral Complexes
27.9K
Crystal Field Theory
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
27.9K
Crystal Field Theory - Tetrahedral and Square Planar Complexes
44.7K
Tetrahedral Complexes
Crystal field theory (CFT) is applicable to molecules in geometries other than octahedral. In octahedral complexes, the lobes of the dx2−y2 and dz2 orbitals point directly at the ligands. For tetrahedral complexes, the d orbitals remain in place, but with only four ligands located between the axes. None of the orbitals points directly at the tetrahedral ligands. However, the dx2−y2 and dz2 orbitals (along the Cartesian axes) overlap with the ligands less than the dxy,...
Crystal field theory (CFT) is applicable to molecules in geometries other than octahedral. In octahedral complexes, the lobes of the dx2−y2 and dz2 orbitals point directly at the ligands. For tetrahedral complexes, the d orbitals remain in place, but with only four ligands located between the axes. None of the orbitals points directly at the tetrahedral ligands. However, the dx2−y2 and dz2 orbitals (along the Cartesian axes) overlap with the ligands less than the dxy,...
44.7K
Complexation Equilibria: The Chelate Effect
661
In complexation reactions, metal atoms or cations interact with ligands to form donor-acceptor adducts called metal complexes. Ligands that bind through one donor site are monodentate, ligands with two donor sites are bidentate, and those with more than two donor sites are polydentate ligands. For example, ethylene diamine is a bidentate ligand that binds through two nitrogen donor atoms, forming a five-membered ring. EDTA is a polydentate ligand that binds through four oxygen and two nitrogen...
661
Effects of Chemicals: Overview
1.4K
Drugs, encompassing various chemical compounds from natural sources, lab synthesis, or genetic engineering, elicit different biological responses in living organisms. Some of these responses are desirable or therapeutic, while others are undesirable. The primary goal of administering a drug is to achieve a therapeutic effect, that is, to address a specific disease or health condition. Any concurrent effects outside of this therapeutic outcome are considered undesirable. These undesirable...
1.4K
Local Anesthetics: Adverse Effects
492
While local anesthetics are generally safe and well-tolerated, they can occasionally cause adverse effects that vary in severity. Local anesthetics can induce toxicity at two distinct levels. They can either produce local effects through direct contact with the neural elements or be absorbed into the bloodstream from the injection site, leading to systemic effects.
Once absorbed into the systemic circulation, local anesthetics can affect the organs that depend on the functioning of sodium...
Once absorbed into the systemic circulation, local anesthetics can affect the organs that depend on the functioning of sodium...
492


