低密度聚乙烯无布在化过程中的再结晶通过化电
Yueming Ren1,2, Changjin Li2, Minqiao Ren2
1College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China.
Polymers
|August 14, 2025
概括
80°C以上的低密度聚乙烯 (LDPE) 非织造布的回火降低了其点,结晶性和拉伸强度. 不同的结晶机制影响微观结构的演变和材料的特性.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物科学 聚合物科学
- 织工程 织工程 织工程
背景情况:
- 化电是生产无布的关键技术.
- 了解低密度聚乙烯 (LDPE) 等聚合物的热行为对于优化材料性能至关重要.
研究的目的:
- 研究热温度对LDPE无布微观结构和拉伸性能的影响.
- 阐明在化过程中控制微观结构变化的再结晶机制.
主要方法:
- 差分扫描热量计 (DSC) 用于热分析.
- 小角度X射线散射 (SAXS) 用于微观结构的表征.
- 扫描电子显微镜 (SEM) 用于表面形态.
- 用于数据分析的高斯函数适配.
主要成果:
- 80°C以上的回火降低了LDPE的点和结晶度.
- 无布的拉伸强度和叶片分布受到80°C以上火的负面影响.
- 确定了二次和自发结晶的两种再结晶机制,它们的优势取决于热温度.
结论:
- 这项研究提供了一个物理模型,用于微结构进化化LDPE无布.
- 这些发现解释了观察到的微观结构和拉伸特性变化.
- 优化回火条件对于量身定制LDPE无布性能至关重要.
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