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使用ICHEM技术对基于胆化物的深性溶剂进行双相连续化:迈向具有潜在抗腐蚀性质的新热物的一步
Qing Liu1, Philippe Vermaut2, Irene Malpartida3
1ChimieParisTech, PSL Research University, CNRS, Institute of Chemistry for Life and Health Sciences, 11 rue Pierre et Marie Curie, Paris, F-75005, France.
Chemistry (Weinheim an der Bergstrasse, Germany)
|August 14, 2025
概括
连续流加热的机械化学使得深度性溶剂 (DESs) 的第一个双相化成为可能,产生了具有高效率和最小性质变化的新型水热DESs. 这些新的DES还显示出作为有效的腐蚀抑制剂的前景.
科学领域:
- 绿色化学 绿色化学
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 深度浸泡溶剂 (DES) 为各种应用提供可调节的性能.
- 对于DESs来说,传统的合成方法可能是低效和环境负担.
- 开发具有增强功能的新型DES,如水热性和抗腐蚀性,具有显著的兴趣.
研究的目的:
- 通过连续流加热机械化学 (ICHEM) 方法合成新型的热性DES.
- 调查ICHEM双相化过程的效率和可扩展性.
- 评估合成的DESs的物理化学特性和抗腐蚀潜力.
主要方法:
- 基于胆化的DESs与乙,六和八无水化物的双相化.
- 在批量模式中优化反应,然后使用ICHEM反应器扩大到连续流量.
- 物理化学性能的分析和抗腐蚀性能的评估.
主要成果:
- 通过连续流化成功合成了三种新型的热水性DESs.
- 在实验室尺度 (50-100克) 中使用ICHEM工艺获得高产量 (90-95%).
- 与批量方法相比,ICHEM过程对DES物理化学性质的影响最小.
- 合成的DES表现出作为腐蚀抑制剂的显著有效性.
结论:
- ICHEM技术提供了一种高效且可扩展的方法,用于合成新型的热气体DES.
- 合成的DES具有理想的物理化学特性,并表现出强大的抗腐蚀活性.
- 这项研究突出了ICHEM在开发功能化DES的潜力,用于先进的应用,包括腐蚀抑制.
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