在25-350°C和0.1-40 MPa的形式盐溶液的定量现场拉曼分析:对形式盐分布在地球上的影响
Shichuan Xi1, Ruifang Huang2, Zhendong Luan3
1Laoshan Laboratory, Qingdao 266237, China.
概括
酸盐 (HCOO-) 在高达300°C的温度下是稳定的,在350°C以上慢慢分解. 这一发现表明,酸盐是地质环境中普遍存在的源.
科学领域:
- 地质化学 地质化学
- 微生物学 微生物学
- 地质地质地质地质地质地
背景情况:
- 格式 (HCOO-) 在高温地质环境中普遍存在.
- 它的热稳定性和在现场进行的定量分析不太清楚.
- 格式支持深层岩层中的微生物群落.
研究的目的:
- 开发一个定量拉曼模型用于现场格式分析.
- 确定酸盐 (NaHCOO) 溶液的热稳定性.
- 评估酸盐作为地质环境中的源的作用.
主要方法:
- 开发了一个Raman定量模型用于格式 (25350 °C,0.140 MPa).
- 使用与水的线性关系校准在位格式度.
- 在不同温度和压力下研究了NaHCOO溶液的稳定性.
主要成果:
- NaHCOO溶液在高达300°C的温度下保持稳定.
- 在350°C以上,分解为H2和CO2发生.
- 在350°C时,甲酸盐的分解速度明显低于之前报告的速度.
结论:
- 在地质环境中,非生物形式可能更普遍.
- 酸盐在深层石化层中作为一个重要的源.
- 开发的拉曼模型能够准确地在现场进行量化.
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