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Updated: Sep 11, 2025

Amide Coupling Reaction for the Synthesis of Bispyridine-based Ligands and Their Complexation to Platinum as Dinuclear Anticancer Agents
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Amide Coupling Reaction for the Synthesis of Bispyridine-based Ligands and Their Complexation to Platinum as Dinuclear Anticancer Agents

Published on: May 28, 2014

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一种三脚四牙联体体,具有硫胺桥头和灵活电荷的

Soumitra Dinda1, Mathias L Skavenborg1, James N McPherson1

  • 1Department of Physics, Chemistry and Pharmacy, University of Southern Denmark, Campusvej 55, 5230 Odense M, Denmark.

ACS omega
|August 18, 2025
PubMed
概括

合成了一种新型的三脚四牙联体与二次硫胺组. 它的铁,和复合体表现出独特的协调和反应性,为金属 - 连接体相互作用提供了洞察力.

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The hybridized nitrogen atom in amines possesses a lone pair of electrons and is bound to three substituents with a bond angle of around 108°, which is less than the tetrahedral angle of 109.5°. However, the C–N–H bond angle is slightly larger at 112°, with a carbon–nitrogen bond length of 147 pm. This carbon–nitrogen bond length of of amines is longer than the carbon–oxygen bond of alcohols (143 pm) but shorter than alkanes’...
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Structure of Carboxylic Acid Derivatives
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