硫酸盐基凝固剂可以抑制处理过的油砂细尾矿中的甲生成
Philip A Adene1, Mojtaba Abdolahnezhad1, Mian N Anwar2
1Department of Geological Sciences, University of Saskatchewan, 114 Science Place, Saskatoon, SK, S7N 5E2, Canada.
Geochemical transactions
|August 18, 2025
概括
液体细尾中的硫酸盐基凝固剂刺激微生物硫酸盐的减少,抑制甲的产生. 在硫酸盐耗尽后,甲生产恢复,突出显示了尾矿处理中的复杂生物地化学相互作用.
科学领域:
- 环境科学 环境科学
- 微生物学 微生物学
- 地质化学 地质化学
背景情况:
- 来自矿开采的细流体尾矿 (FFT) 需要回收.
- 化学凝固剂和花剂用于FFT脱水.
- 这些化学物质对FT生物地质化学的影响尚未完全理解.
研究的目的:
- 检查硫酸盐基凝固剂对FT中的生物气体生产的影响.
- 调查受治疗的FFT中的微生物群落的影响.
- 了解回收尾矿中的生物地质化学过程.
主要方法:
- 在FFT上进行了无氧批量实验.
- 应用了不同剂量 (0,500,1000,1500 ppm) 的硫酸,硫酸铁和硫酸.
- 分析了生物性气体生产和微生物群落 (16S rRNA测序).
主要成果:
- 添加硫酸盐刺激了微生物的硫酸盐减少,抑制了甲基生成.
- 在一些实验中 (例如,石膏),硫酸盐耗尽之前产生了甲.
- 较高的凝固剂剂量导致硫酸盐度增加和pH值下降;硫化铁沉限制了H2S.
结论:
- 硫酸盐基凝固剂可以改变FFT中的微生物硫酸盐减少和甲基生成.
- 碳,硫和铁循环之间的复杂相互作用影响尾矿处理结果.
- 生物地质化学考虑对于开发有效的尾矿管理技术至关重要.
相关概念视频
Bioremediation
20.0K
Bioremediation is the use of prokaryotes, fungi, or plants to remove pollutants from the environment. This process has been used to remove harmful toxins in groundwater as a byproduct of agricultural run-off and also to clean up oil spills.
20.0K
Coagulation
374
Colloidal solids are solid particles suspended in solution. They are usually negatively charged, attracting a compact primary layer of positively charged ions, which attract more counterions to form an electrical double layer. Electrostatic repulsion between the charged double layers prevents the particles from colliding, stabilizing the colloids. These solids are often undesirable because they can contain toxins that are difficult to remove. Coagulation is a technique that helps aggregate and...
374
Metabolism of Chemolithotrophs
167
Chemolithotrophs are microorganisms that obtain energy by oxidizing inorganic molecules such as hydrogen gas (H₂), ammonia (NH₃), reduced sulfur compounds (H₂S, S²⁻), and ferrous iron (Fe²⁺). Unlike heterotrophic organisms that rely on organic carbon, chemolithotrophs transfer electrons from these inorganic donors to the electron transport chain (ETC), generating a proton motive force (PMF) that drives ATP synthesis through oxidative phosphorylation.
167
Colloidal precipitates
749
The high insolubility of some precipitates can result in an unfavorable relative supersaturation. This can lead to colloidal particles with a large surface-to-mass ratio, where adsorption is promoted. For instance, in the precipitation of silver chloride, silver ions are adsorbed on the surface of the colloidal particles, forming a primary layer. This layer attracts ions of opposite charge (such as nitrate ions), forming a diffuse secondary layer of adsorbed ions. This electric double layer...
749
Precipitation and Co-precipitation
2.0K
Precipitation and coprecipitation methods can be used to separate a mixture of ions in a solution. In qualitative inorganic analysis, ions that form sparingly soluble precipitates with the same reagent are separated based on the differences in solubility products. For example, consider the separation of Cu(II) and Fe(II) ions by precipitation as insoluble sulfides. First, copper(II) sulfide is precipitated by the addition of acidic H2S, where the dissociation of H2S is suppressed. Adding H2S...
2.0K


