使用纳米层材料处理废水中的咖啡因:对过程动力学,建模和毒性评估的综合研究
Nabila Shehata1, Fatma I Abo El-Ela2, Simranjeet Singh3
1Environmental Science and Industrial Development Department, Faculty of Postgraduate Studies for Advanced Science (PSAS), Beni-Suef University, P.O. Box 62511, Beni-Suef, Egypt.
Journal of environmental management
|August 19, 2025
概括
水泥粉 (CKD) 有效地从水中去除咖啡因 (CAF). 这种工业废物具有很高的吸附能力和快速平衡,pH值变化对去除过程的影响最小.
科学领域:
- 环境科学 环境科学
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 咖啡因 (CAF) 是一种常见的水污染物.
- 工业废物,如水泥炉灰尘 (CKD),存在处理方面的挑战.
- 开发可持续的污染物清除方法至关重要.
研究的目的:
- 为了研究加工水泥炉粉尘 (CKD) 从水溶液中去除咖啡因 (CAF) 的功效.
- 为了优化吸附参数,包括pH值,时间,初始度和CKD剂量.
- 描述吸附机制和评估CKD在咖啡因吸附前后的细胞毒性.
主要方法:
- 进行了批量吸附实验,以评估CKD的CAF去除.
- 吸附参数 (pH,时间,度,剂量) 被系统优化.
- 使用FTIR,XRD和SEM进行了材料表征.
- 吸附动力学和异热量是使用各种既有模型建模的.
- 细胞毒性使用转型人肝上皮细胞-2 (THLE-2) MTT试验进行了评估.
主要成果:
- 对CKD的CAF吸附在广泛范围 (pH 2-9) 上是pH独立的,并在5分钟内实现了快速平衡.
- 最大吸附能力达到令人印象深刻的1769.03毫克CAF/g的CKD.
- 吸附动力学被伪第一和第二阶段模型描述得很好,等温模型显示了高的相关系数.
- CKD表现出低细胞毒性 (IC50 = 306.9 μg/mL),在咖啡因吸附后显著降低 (IC50 = 771.1 μg/mL).
结论:
- 经过加工的水泥粉 (CKD) 是一种高效和高效的吸附剂,可以从水中去除咖啡因 (CAF).
- 吸附过程是快速的,不依赖pH值,并表现出高容量,使CKD成为一个有前途的可持续吸附剂.
- CKD表现出有利的细胞毒性概况,表明在水处理应用中安全重复使用的潜力.
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