在基辅助聚胺膜中选择性运输能量障碍,以实现高效的Cl-/SO42-选
Xiaoming Xu1,2, Zhiwei Wang1, Guoyan Hua1
1State Key Laboratory of Water Pollution Control and Green Resource Recycling, School of Environment, Nanjing University, Nanjing 210023, China.
Environmental science & technology
|August 23, 2025
概括
这项研究引入了一种新型的素辅助纳米过膜 (NF) 用于淡化水. 这种工程膜显著改善了化物和硫酸盐的分离,为水资源短缺提供了可持续的解决方案.
科学领域:
- 材料科学
- 化学工程
- 环境科学
背景情况:
- 纳米过 (NF) 膜对于海水淡化至关重要,但在平衡透和排放方面面临挑战.
- 聚胺 (PA) NF膜的选择性权衡限制了它们在解决全球水资源短缺方面的效率.
研究的目的:
- 为PA NF膜开发先进的离子传输障碍物.
- 通过调节孔隙结构和表面电荷来提高NF膜的性能.
主要方法:
- 使用碳化基纳米纤维 (CO-ChNF) 作为中间层构建了基辅助的PA NF膜.
- 纳入生物质衍生CO-ChNF以控制界面聚合并增强膜性质.
- 通过分析离子脱水和静电排斥能量来研究离子选机制.
主要成果:
- 设计的CO-ChNF/PA膜表现出更明显的孔径分布和更高的电荷密度.
- 达到了31.4 L m-2 h-1 bar-1的透度和高Cl−/SO42−的选择性.
- 在Cl−/SO42−分离中表现优于大多数商业和报告的NF膜.
结论:
- 基辅助界面聚合是一种提高NF膜性能的创新方法.
- 开发的膜为化物/硫酸盐选提供了有效的方法,有助于改进水处理技术.
相关概念视频
Ion Exchange
658
Ion exchange chromatography separates charged molecules from a solution by reversibly exchanging them with mobile, or 'active', ions associated with the oppositely charged stationary phase. This method can be used to separate ions, soften and deionize water, and purify solutions. The polymers comprising the ion-exchange column are high-molecular-weight and chemically stable polymers, crosslinked to be porous and essentially insoluble. They are also functionalized with either acidic or...
658
Facilitated Diffusion
609
The plasma membrane, a critical structure in cellular biology, houses an array of transporters, or carrier proteins, interspersed within its lipid bilayer. These proteins play a crucial role in solute transport through facilitated diffusion, a form of passive diffusion that uses transporters to move the molecules across the membrane.
In this process, substrates such as organic compounds and ions interact with a transporter on one side, triggering conformational changes in proteins that enable...
In this process, substrates such as organic compounds and ions interact with a transporter on one side, triggering conformational changes in proteins that enable...
609
Pore Transport and Ion-Pair Transport
639
Pore transport and ion-pair formation are critical mechanisms for the absorption and distribution of drugs in the body.
Pore transport, also known as convective transport, is a process where small molecules like urea, water, and sugars rapidly cross cell membranes as though there were channels or pores in the membrane. Although direct microscopic evidence is limited but the concept of pores or channels is widely accepted based on physiological evidence. Despite the lack of direct...
Pore transport, also known as convective transport, is a process where small molecules like urea, water, and sugars rapidly cross cell membranes as though there were channels or pores in the membrane. Although direct microscopic evidence is limited but the concept of pores or channels is widely accepted based on physiological evidence. Despite the lack of direct...
639
Detergent Purification of Membrane Proteins
5.3K
Detergents are used to purify the integral proteins of the membrane. The hydrophobic portion of the detergent can replace membrane phospholipids while solubilizing the membrane proteins. When detergent monomers reach a specific concentration in a solution called critical micelle concentration (CMC), they form micelles. Above CMC, the concentration of the detergent monomers remains in equilibrium with the micelle. The number of detergent monomers present in the CMC varies for each detergent, and...
5.3K
The Significance of Membrane Transport
29.5K
The transport of solutes across the cell membrane is essential for metabolic processes, like maintaining cell size and volume, generating the action potential, exchanging nutrients and gases, etc. Membrane transport can be either passive or active. It can be simple diffusion, facilitated, or mediated transport aided by transport proteins such as transporters and channels.
Transporters facilitate either an active or passive movement of solutes. They can allow a single-molecule transport down its...
Transporters facilitate either an active or passive movement of solutes. They can allow a single-molecule transport down its...
29.5K
Dialysis
805
Dialysis is a diffusion-based purification process that separates analyte molecules from a complex matrix. This is accomplished by allowing molecules in the solution to pass through a semipermeable membrane into a liquid on the other side. The membrane is usually made of cellulose acetate or cellulose nitrate, and the second liquid must be miscible with the solution. Ions (e.g., chloride or sodium) or organic molecules (e.g., glucose) can pass through the membrane pores, which generally have...
805


