酸玻璃的紫外线-C上转光
Kento Takayama1,2, Yuuki Kitagawa1, Kenji Shinozaki1
1Department of Materials and Chemistry, National Institute of Advanced Industrial Science and Technology (AIST), Ikeda, Osaka 563-8577, Japan.
ACS omega
|August 25, 2025
概括
新的酸玻璃添加Pr3+显示承诺的紫外线 (UV) 灭菌. 这些材料表现出蓝色至紫外线C (UVC) 升级的发光,这对于开发先进的紫外线消毒技术至关重要.
科学领域:
- 材料科学
- 发光效应
- 光学工程
背景情况:
- 对于有效的紫外线 (UV) 灭菌的日益增长的需求需要在UVC频谱 (100-280nm) 中发射新的发光材料.
- 已使用Pr3+的材料正在研究其上转换 (UC) 特性,但存在诸如度火等挑战.
研究的目的:
- 开发和描述用Pr3+合的酸盐玻璃,用于蓝色到UVC的升级发光.
- 评估这些眼镜在紫外线消毒应用中的光学性能和潜力.
主要方法:
- 用不同的Pr3+度合的酸玻璃用灭方法合成.
- 分析了包括吸收和发光光谱在内的光学特性.
- 在不同的激发波长下研究了上转光.
主要成果:
- 在180纳米激发下,Pr3+酸玻璃在UVC区域 (4f1 5d1 → 4f2过渡) 呈现出广泛的发光带.
- 在用455nm蓝色激光激发时,观察到蓝色到UVC的升级发光在276nm达到峰值.
- 由于度灭和交叉放松,光发强度在0.1%以上显著下降.
结论:
- 与氧化陶和玻璃相比,酸玻璃具有更高的4f1 5d1能量水平.
- 这些材料是蓝色到紫外线升级的有希望的候选材料,通过组合优化为新型紫外线消毒技术提供了潜力.
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