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用于检测Fe²⁺和Pb²⁺离子的可逆色度和光"关闭"探针

M Jyothi Priya¹, Hosakere D Revanasiddappa², B Jayalakshmi³

¹Department of Studies in Chemistry, University of Mysore, Manasagangotri, Mysuru, Karnataka, 570 006, India.

Scientific reports

|August 25, 2025

概括

一种基于eugenol的新型传感器, (E) -N'-(5-allyl-2-hydroxy-3-methoxybenzylidene) --2-hydroxybenzohydrazide (EABH),可以对铁 (Fe2+) 和 (Pb2+) 离子进行敏感的色度检测.

科学领域:

化学传感器
分析化学
材料科学

背景情况:

欧原醇衍生物为开发化学传感器提供了多功能平台.
对Fe2+和Pb2+等金属离子的选择性和敏感检测对于环境和生物监测至关重要.
现有的金属离子检测方法可能复杂且昂贵.

研究的目的:

合成和表征一种基于eugenol的新型化学传感器, (E) -N'-(5-基-2-基-3-甲基利丁) -2-基化 (EABH).
研究EABH对Fe2+的色度检测和Pb2+的度检测的双重传感能力.
评估传感器在生物成像和现实世界样品中的灵敏度,选择性和适用性.

主要方法:

EABH的合成和光谱表征 (NMR,质谱).
用于检测Fe2+和Pb2+的色度测试和度测试.
活细胞成像,棉花棒和测试纸的应用.
计算研究 (FMO,MEP),以了解相互作用机制.

主要成果:

EABH显示了Fe2+的明显颜色变化 (黄色到棕色) 和Pb2+的光"关闭"反应.
对于Fe²⁺的检测极限为0.166μM,对于Pb²⁺的检测极限为0.095μM.
在活细胞成像和实践样本分析中成功应用在棉条和试验纸上.

结论:

EABH是一种强大的有效化学传感器,用于选择性Fe2+和Pb2+检测.
这种传感器对生物成像和成本效益的环境监测有很大的潜力.
计算研究提供了有关传感器反应和交互点的见解.

关键词:

一个 DFT 欧根醇光灭可持续发展目标6 飞船基地有毒金属

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