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Updated: Sep 10, 2025

Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes
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光促进的C-C) 从二甲基NiII复合体的减少消除

Alexander Q Cusumano1, Braden C Chaffin1, David A Cagan2

  • 1Department of Chemistry and Biochemistry, University of California Los Angeles, Los Angeles, California 90095, United States.

Journal of the American Chemical Society
|August 26, 2025
PubMed
概括

光激活使催化C ((sp3) -C ((sp3)) 键形成,通过克服来自Ni ((II) 复合物的具有挑战性的还原性消除. 这种光解/激素反弹机制为难以交叉合的反应提供了新的策略.

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