双发光Sc2(MoO4)3:Dy3+/Eu3+光系统:能量转移动态和高灵敏度的温度传感
Zhengrong Xia1, Rongqing Li1, Fangfang Liu1
1Anhui Engineering Research Center for Photoelectrocatalytic Electrode Materials, School of Electrical Engineering, Huainan Normal University Huainan 232038 China wwzhou@hnnu.edu.cn.
RSC advances
|August 27, 2025
概括
新的双 (Dy3+) 和欧 (Eu3+) 联合合酸 (SMO) 光学温度计具有前景. 这些材料具有高效的能量传输和高灵敏度的温度传感应用.
科学领域:
- 材料科学
- 固态化学
- 发光效应
背景情况:
- 酸 (Sc2(MoO4) 3,SMO) 是一个有希望的的宿主材料.
- 稀土离子兴奋剂 (Dy3+, Eu3+) 可以调整特定应用的发光特性.
研究的目的:
- 合成和表征Dy3+/Eu3+配的SMO.
- 研究Dy3+和Eu3+之间的能量传递机制.
- 评估这些光的潜力以进行比度光学温度测量.
主要方法:
- 固态反应合成
- 用瑞特维尔德精细化进行相位和结构分析的X射线衍射 (XRD).
- 扫描电子显微镜 (SEM) 用于形态学.
- 密度功能理论 (DFT) 的计算和电子结构的扩散反射光谱.
- 光发光光谱学和光发光衰变动力学,用于光学特性和能量转移.
主要成果:
- 我们成功地合成了纯相体晶体.
- 在紫外线激发下,使用Dy3+的SMO显示出特征性排放.
- 在辅助剂样本中证实了Dy3+向Eu3+的有效能量转移.
- 优化的SMO:Dy3+,Eu3+获得了较高的相对和绝对温度灵敏度.
结论:
- 具有Dy3+/Eu3+的SMO光体是有效的发光材料.
- 有效的 Dy3+ 到 Eu3+ 的能量转移促进了可调节的发光.
- 这些体显示出精确的比度光学温度计的巨大潜力.
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