开发一种以超声波辅助的泥采样为基础的方法,用于使用FAAS确定大米样本中的金属
Lays Pereira do Nascimento1, Laís Silva Gomes1, Cleber Galvão Novaes1
1Departamento de Ciências E Tecnologias, Universidade Estadual Do Sudoeste da Bahia, Campus de Jequié, Rua José Moreira Sobrinho s/n, 45.206-190, Jequié, Bahia, Brazil.
Biological trace element research
|August 27, 2025
概括
一种使用泥取样的新绿色分析方法可以准确地确定大米中的,铁和. 这种方法可以准确可靠地量化食品样本中的必需矿物质.
科学领域:
- 分析化学
- 环境科学
- 食品科学
背景情况:
- 准确确定米中的 (Ca),铁 (Fe) 和 (Zn) 等必需矿物质对于人类营养和健康至关重要.
- 食品矩阵中的传统元素分析方法通常涉及复杂的样本制备,产生大量的废物.
- 开发绿色和高效的分析技术对于最小化环境影响和改善分析工作流程至关重要.
研究的目的:
- 开发和优化一种绿色分析方法,用于确定米样中的Ca,Fe和Zn.
- 使用泥采样与多变量优化相结合,以提高方法性能.
- 验证该方法是否适用于常规样分析.
主要方法:
- 使用0.7mol L-1 HNO3和0.31% Triton X-100的0.25g大米样本进行泥采样技术.
- 进行超声波浴处理7.5分钟以有效地使样品均化.
- 多变量优化使用两级分数因数设计和多勒特设计来确定最佳的实验条件.
主要成果:
- 对Ca (4.9毫克/kg),Fe (1.6毫克/kg) 和Zn (0.22毫克/kg) 达到了低量化限度 (LOQ).
- 证明高精度,可重复性值为4.4% (Ca),3.6% (Fe) 和2.2% (Zn) (n=7).
- 通过尖峰测试 (90-108%的回收) 证实了准确性,与标准酸分解方法 (配对t测试,95%的置信度) 相比,差异在统计上是微不足道的.
结论:
- 开发的绿色泥采样方法对于确定大米中的Ca,Fe和Zn是准确,精确和高效的.
- 这种方法为传统技术提供了可持续的替代方案,减少了样本准备时间和废物产生.
- 经过验证的方法适用于常规分析中的必需矿物质,有助于食品质量和安全性评估.
相关概念视频
Atomic Absorption Spectroscopy: Lab
556
For AAS measurements, samples must be introduced as clear solutions, often requiring extensive preliminary treatment to dissolve materials like soils, animal tissues, and minerals. Common methods for sample preparation include treatment with hot mineral acids, wet ashing, combustion in closed containers, high-temperature ashing, or fusion with reagents.
Solutions containing organic solvents, such as low-molecular-mass alcohols, esters, or ketones, enhance absorbances by increasing...
Solutions containing organic solvents, such as low-molecular-mass alcohols, esters, or ketones, enhance absorbances by increasing...
556
Atomic Fluorescence Spectroscopy
496
Atomic fluorescence spectroscopy (AFS) is an analytical technique that involves the electronic transitions of atoms in a flame, furnace, or plasma being excited by electromagnetic (EM) radiation. When these atoms absorb energy, they become excited and subsequently release energy as they return to their original state. This emitted light, or "fluorescence," is observed at a right angle to the incident beam. Both absorption and emission processes transpire at distinct wavelengths, which...
496
Atomic Absorption Spectroscopy: Overview
2.4K
Atomic absorption spectroscopy (AAS) is a technique used to analyze elements by measuring electromagnetic radiation (EMR) absorbed by atoms, which causes them to transition to a higher-energy orbit. The most crucial step in AAS is atomization, where the analyte is converted into gas-phase atoms, typically through a flame or furnace. Some of these atoms become thermally excited in the flame, while most remain in the ground state.
When irradiated by EMR of a particular wavelength, these...
When irradiated by EMR of a particular wavelength, these...
2.4K


