高面积密度和稳定的Pt单原子电催化剂通过弧度放电原子化和Coni捕获的简单合成
Hongzhe He1,2, Xiaoqiong Ren3,2, Ruoqun Zhang1,2
1Department of Chemical and Biological Engineering, Monash University, Victoria, 3800, Australia.
Advanced science (Weinheim, Baden-Wurttemberg, Germany)
|August 28, 2025
概括
研究人员开发了一种新方法来合成高密度和热稳定的单原子催化剂 (SAC). 这一突破推动了SAC在生产等清洁能源技术中的应用.
科学领域:
- 材料科学
- 催化剂
- 纳米技术
背景情况:
- 单原子催化剂 (SAC) 对于高效的电催化是至关重要的.
- 在SAC中实现高单原子面积密度和热稳定性是一项挑战.
- 类金属SAC在电催化应用中非常受欢迎.
研究的目的:
- 为具有高面积密度的单原子催化剂 (SAC) 开发一种简单可扩展的合成策略.
- 研究这些新型SAC的结构完整性和电催化性能.
- 为潜在的清洁能源应用展示合成方法的普遍性和可扩展性.
主要方法:
- 为快速可扩展的合成提供真空直流弧放电 (DCAD) 策略.
- 在CoNi纳米合金上固定单个原子并用碳纳米管 (CoNiPtSA@G) 封闭.
- 催化剂结构,组成和高达1000°C的热稳定性.
- 电化学测试演变反应 (HER) 的性能和长期稳定性.
主要成果:
- 获得了前所未有的Pt单原子面积密度10.6原子/nm2与3.82%的Pt负荷.
- 由于强大的电子捕获,证明了高达1000°C的特殊热稳定性.
- 在10mA/cm2时表现出23mV的超电位和比Pt/C高5倍的质量活性.
- 证明了DCAD对其他金属如的普遍性,并在0.5小时内实现了克尺度的产量.
结论:
- 该方法为大规模生产高密度,耐热SAC提供了开创性的途径.
- 合成的CoNiPtSA@G催化剂显示出在清洁能源技术,特别是生产中的实用应用的巨大潜力.
- 这项工作克服了关键的合成挑战,为先进的催化材料铺平了道路.
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