从多元氧化玻璃结晶的酸基玻璃陶:相位组成和微观结构
Ruzha Harizanova1, Wolfgang Wisniewski2,3, Dragomir M Tatchev4
1Physics Department, University of Chemical Technology and Metallurgy, 8 Kl. Ohridski Blvd., 1756 Sofia, Bulgaria.
Materials (Basel, Switzerland)
|August 28, 2025
概括
新的介电玻璃陶被合成用于电子应用. 控制的结晶产生了具有高介电常数 (≥100) 和中等损耗的材料,显示了先进电子元件的潜力.
科学领域:
- 材料科学
- 固态化学
- 介电材料
背景情况:
- 在电子和传感器设备中对先进介电材料的需求不断增长.
- 需要具有针对电子元件的特性的新型玻璃陶.
研究的目的:
- 在Na2O/Al2O3/BaO/ZrO2/TiO2/B2O3/SiO2系统中合成和描述新型介电玻璃陶.
- 研究受控热处理对结晶和微观结构的影响.
- 评估潜在电子应用的介电性质.
主要方法:
- 玻璃合成的融化灭技术.
- 在玻璃陶中进行可控的热处理.
- 用于相位识别的X射线衍射 (XRD).
- 扫描电子显微镜 (SEM) 用于微观结构分析.
- 微计算机X射线断层扫描 (μCT) 用于体积分析.
- 阻抗光谱用于介电性质的评估.
主要成果:
- 成功合成含有Ba2TiSi2O8 (弗雷斯诺石) 和BaTiO3 (可能是BaZrxTi1-xO3固体溶液) 的玻璃陶.
- 微观结构的特点是果形状,密集分支的结晶结构.
- 结晶体体积分数和平均尺寸随着时间的延长而增加.
- 介电性质表现出高介电常数 (≥100) 和中等损失触点的绝缘行为.
结论:
- 合成的玻璃陶对电子应用具有理想的介电性质.
- 热处理参数显著影响微观结构和介电性能.
- 这些材料是电子设备中先进的介电元件.
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