地质聚合物化学和组成:以可持续建筑为导向的综合,反应机制和材料特性
Sri Ganesh Kumar Mohan Kumar1, John M Kinuthia1, Jonathan Oti1
1Faculty of Computing, Engineering and Science, University of South Wales, Pontypridd CF37 1DL, UK.
Materials (Basel, Switzerland)
|August 28, 2025
概括
与普通波特兰水泥相比,可持续的活性材料 (AAM) 的碳排放量更低,耐用性更强. 这一审查巩固了地质聚合物化学,性能和可持续建筑的应用方面的进展.
科学领域:
- 材料科学
- 绿色化学
- 土木工程
背景情况:
- 地质聚合物是从前体中获得的可持续低活性材料 (AAM).
- 它们为环境带来好处,如减少碳足迹和工业副产品的价值.
- 与普通波特兰水泥 (OPC) 相比,地质聚合物在恶劣环境中具有更高的耐用性.
研究的目的:
- 对地质聚合物化学,组成和反应机制进行批判性审查.
- 评估微观结构与性能之间的关系和耐用性挑战.
- 探索与联合国可持续发展目标 (SDGs) 相一致的新兴应用.
主要方法:
- 对前体反应性,摩尔比 (Si/Al),激活剂化学和固化方案的分析.
- 酸 (AAS) 和酸 (ASP) 系统的比较研究.
- 对微结构证据 (SEM,XRD) 和耐久性问题 (ASR,收缩) 的评估.
主要成果:
- 热力学建模和机器学习 (ML) 的进步有助于前体选择和混合设计.
- 了解反应机制对于优化地质聚合物微观结构和性能至关重要.
- 诸如-反应 (ASR) 和收缩等耐用性挑战需要谨慎管理.
结论:
- 地质聚合物技术符合循环经济原则,
- 需要进一步研究混合设计标准化,新型前体的LCA和可变性管理.
- 地质聚合物对基础设施弹性和从路面到生物医疗植入物的各种应用具有重大潜力.
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