聚乙烯表面活性剂辅助超临界二氧化碳-石油混合性的影响评估和机制研究
Xin-Wei Jiang1, Cheng Ma2, Gui-Yang Ma1
1College of Petroleum Engineering, Liaoning Petrochemical University, Fushun, Liaoning 113001, China.
Langmuir : the ACS journal of surfaces and colloids
|August 29, 2025
概括
一种新的可见失踪界面测量 (VVIM) 方法简化了对二氧化碳泛滥的最小可混合压力 (MMP) 的确定. 新型聚乙烯表面活性剂增强混合性,提供比传统选择更好的辅助混合效果.
科学领域:
- 石油工程
- 化学工程
- 材料科学
背景情况:
- 降低最低混合压力 (MMP) 对于低透性储和二氧化碳储存至关重要.
- 传统的MMP测定方法昂贵且耗时.
研究的目的:
- 提出一种新的,具有成本效益的实验方法来测量MMP.
- 调查影响超临界CO2 (scCO2) 油混合性的因素.
- 评估聚乙烯表面活性剂的辅助作用.
主要方法:
- 开发了可见界面消失测量 (VVIM) 方法.
- 研究速率,质量比,温度和油性能的影响.
- 评估的聚乙烯表面活性剂如Tween 80,C8PO15EO10和phPO15EO10.
主要成果:
- scCO2-油混合压力与速率和温度相关.
- 在1:1的质量比下,混合性是具有挑战性的.
- 聚乙烯表面活性剂表现出优异的两性和空间匹配,从而提高了混合性.
结论:
- VVIM方法为MMP测量提供了可靠的替代方案.
- 聚乙烯表面活性剂有望提高二氧化碳排放效率.
- 这些发现为scCO2泛滥中的表面活性剂结构-活性关系提供了参考.
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