自催化陶化在透明的耐废性有机涂层中,用于高级防火
Wenhong Jiang1, Haibo Tan1, Kaiyu Tan1
1School of Materials Science and Engineering, Key Laboratory of Guangdong Province for High Property and Functional Polymer Materials, South China University of Technology, No. 381, Wushan Road, Tianhe District, Guangzhou 510640, China.
新的-涂层为文化文物提供了卓越的透明度和防火保护. 这些先进的材料提供了强大的机械性能和优异的耐磨性, 确保文物保存.
科学领域:
- 材料科学
- 涂料技术
- 防火工程
背景情况:
- 保护文化文物需要具有高透明度,机械强度和耐磨性的先进涂层.
- 在保护性涂层中平衡这些关键性能指标是一个重大挑战.
研究的目的:
- 开发一种新的有机-双网络结构,用于协同自催化陶化.
- 创建高透明度,耐磨,耐火涂层的文物保护.
主要方法:
- 使用三甲基酸盐和三甲基西兰合成-涂层的sol-gel加工.
- 机械性能 (9H硬度,曲直径≤2mm),光透度 (高达99.9%),粘附性和阻燃性 (UL-94V-0,LOI35.5%).
主要成果:
- 开发的涂层具有优异的透明度 (99.9%),硬度 (9H),柔性 (曲直径≤2mm),以及对玻璃和陶的粘附性.
- 通过UL-94V-0等级和35.5%的极限氧指数 (LOI) 实现了卓越的防火保护.
- 在暴露在火焰中,迅速形成紧的陶屏障层,确保耐磨性.
结论:
- 双重交联网络结构提高了硬度和灵活性.
- 和 (Si/B/P) 的协同催化作用促进陶网的形成,阻断热和火焰.
- 这种方法为设计先进的透明,耐磨的防火涂层提供了一种多功能策略.
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相关概念视频
Hydroboration-Oxidation of Alkenes
Alkynes to Aldehydes and Ketones: Hydroboration-Oxidation
One of the convenient methods for the preparation of aldehydes and ketones is via hydration of alkynes. Hydroboration-oxidation of alkynes is an indirect hydration reaction in which an alkyne is treated with borane followed by oxidation with alkaline peroxide to form an enol that rapidly converts into an aldehyde or a ketone. Terminal alkynes form aldehydes, whereas internal alkynes give ketones as the final product.
