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Updated: Sep 9, 2025

Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
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Published on: September 18, 2016

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通过可控制的铜和金催化Divinylallenes的多环N-异环的分离合成

Mi Li1, Shi-Jie Liu2, Kua-Fei Wei1

  • 1College of Science, Henan Agricultural University, Zhengzhou 450002, China.

JACS Au
|August 29, 2025
PubMed
概括

铜催化剂可以从divinylallenes中合成新型N-异环,为贵金属提供多功能替代品. 这项研究扩展了金属碳素化学与催化剂控制的选择性和原子经济反应.

关键词:
1,2-N的迁移铜 铜不对称化乙基烯提供者/提供者碳素

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Cycloadditions are one of the most valuable and effective synthesis routes to form cyclic compounds. These are concerted pericyclic reactions between two unsaturated compounds resulting in a cyclic product with two new σ bonds formed at the expense of π bonds. The [4 + 2] cycloaddition, known as the Diels–Alder reaction, is the most common. The other example is a [2 + 2] cycloaddition.
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