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Updated: Sep 9, 2025

Ammonia Synthesis at Low Pressure
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Ammonia Synthesis at Low Pressure

Published on: August 23, 2017

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在温和条件下通过C─N键构造从塑料废物和氨中合成光催化形式化物

Fulai Liu1,2, Yifei Liang1,2, Xin Zhao3

  • 1Key Laboratory of Photochemical Conversion and Optoelectronic Materials & CAS-HKU Joint Laboratory on New Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing, 100190, P.R. China.

Angewandte Chemie (International ed. in English)
|August 30, 2025
PubMed
概括

这项研究引入了一种新的光催化方法,用于将聚乙烯二甲 (PET) 废物转化为有价值的化学物质. 该过程使用Pt1Au/TiO2催化剂将乙烯基醇与氨结合,产生甲胺和气.

关键词:
甲化物光催化塑料废物聚乙烯二甲

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Direct alkylation is not a suitable method for synthesizing amines because it produces polyalkylated products. Gabriel synthesis is the most preferred method to exclusively make primary amines. The method uses phthalimide, which contains a protected form of nitrogen that participates in alkylation only once to predominantly give primary amines.
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Azide ions act as good nucleophiles and react with unhindered alkyl halides to form alkyl azides. Alkyl azides do not participate in further nucleophilic substitution reactions, thereby eliminating the chances of polyalkylated products. Alkyl azides are reduced by hydride-based reducing agents, like lithium aluminum...
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