构建稳定的地下/表面结构以提高单晶丰富阴极的高循环性
Youqi Chu1,2, Kai Wang3, Changdong Chen1
1Guangzhou Key Laboratory for Surface Chemistry of Energy Materials, New Energy Research Institute, School of Environment and Energy, South China University of Technology, Guangzhou, 510006, P. R. China.
Advanced science (Weinheim, Baden-Wurttemberg, Germany)
|August 30, 2025
概括
这项研究使用双修饰来增强单晶丰富的阴极. 改进的正极显示出高能离子电池的优良结构和电化学稳定性.
科学领域:
- 材料科学
- 电化学
- 电池技术
背景情况:
- 单晶丰富的阴极在高压循环过程中面临过渡金属溶解和相位不稳定等挑战.
- 这些问题限制了高能离子电池的实际应用.
研究的目的:
- 开发单晶LiNi0.90Co0.05Mn0.05O2 (SCNCM90) 阴极的双修改策略.
- 在长时间高压操作下增强结构坚固性和电化学耐用性.
主要方法:
- 实行一个地下Al/B梯度辅助.
- 使用Al5BO9表面涂层.
- 在高电压下进行电化学循环测试.
主要成果:
- 抑制了H2-H3相位过渡,并减少了晶格应变.
- Al5BO9涂层减轻了电极电解质界面反应.
- 经过修改的SCNCM90阴极在4.5V的200个循环后达到95.83%的容量保留,在1C的1000个循环后达到89.6%.
结论:
- 双修饰策略有效地提高了单晶丰富阴极的结构和电化学稳定性.
- 这种方法为下一代高能离子电池提供了有前途的途径.
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