在聚合物基弹性体中可编程超声波调制:实验和构成模型
Ying Geng1, Guoyan Sun2, Sheng Wang1
1School of Mechatronics Engineering, Harbin Institute of Technology, Harbin, 150001, People's Republic of China.
Ultrasonics sonochemistry
|August 30, 2025
概括
超声波振动动态控制聚合物粘性,使其从消散行为转变为弹性行为. 这一突破为先进的材料应用提供了可调节的硬化.
科学领域:
- 软物质力学
- 聚合物科学
- 材料工程
背景情况:
- 在聚合物弹性体中实现可逆和可编程的粘性控制是一个重大挑战.
- 传统方法往往缺乏动态控制和可逆性,限制了精密工程中的应用.
研究的目的:
- 证明超声波振动是聚合物弹性质的动态,可逆和可调节调节方法.
- 阐明机械反应的超声波调制的分子机制.
主要方法:
- 在超声波振动 (19-22 kHz) 下对聚合物弹性体进行单轴压缩实验.
- 使用标准线性固体 (SLS) 模型进行构成和反向建模.
- 对宏观机械变化的分析和与分子动态的相关性.
主要成果:
- 超声波振动诱导一种可逆转变,从粘弹性到弹性主导的行为.
- 观察到显著抑制粘弹性放松和能量消散.
- 实现了可调整的可逆硬化,瞬时弹性模量增加了20%,延迟模量和粘度减少了80%以上.
结论:
- 超声波振动为精确控制聚合物弹性体粘性提供了一个新的机制.
- 这些发现为设计适应性聚合物系统的先进应用提供了实用见解.
- 潜在的应用包括超声波辅助抛光,软机器人和灵活的电子产品.
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