改性粉/聚乙烯基合甲酸薄膜:加工技术在实现高粉含量和高性能方面的作用
Jie Zhang1, Yunsong Liu1, Zhaoyang Niu1
1Key Laboratory for Ultrafine Materials of Ministry of Education, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237, PR China.
International journal of biological macromolecules
|August 30, 2025
概括
这项研究优化了改性粉 (MS) 和聚乙烯基合甲 (PBAT) 复合材料的加工. 通过内部混合机和挤出机的联合方法,获得了高性能可生物降解薄膜,含粉量为60%.
科学领域:
- 材料科学
- 聚合物科学
- 可持续的材料
背景情况:
- 接口兼容和加工优化是复合材料增强的关键.
- 改性粉 (MS) 和聚乙烯基合甲 (PBAT) 复合材料为生物降解薄膜提供了潜力.
- 在高粉含量复合材料中实现强大的兼容性和可加工性仍然是一个挑战.
研究的目的:
- 研究不同加工技术对改性粉 (MS) /聚乙烯 (PBAT) 复合物的可加工性的影响.
- 为了使高粉含量可生物降解薄膜的连续吹.
- 为了优化改性粉和PBAT之间的界面兼容性.
主要方法:
- 使用聚氨预聚合物 (PUP) 制备改性粉.
- 使用各种技术,包括内部混合和挤压加工MS/PBAT复合材料.
- 高粉含量的MS/PBAT薄膜是通过单螺丝吹薄膜挤出生产的.
- 评估了机械,热和质性质.
主要成果:
- 最好的处理包括15分钟的内部混合,然后在薄膜吹之前挤出.
- 这种优化的复合膜具有10.5MPa的抗拉强度,优异的加工性和热稳定性.
- 内部机和双螺杆挤出机的组合有效地解决了加工挑战.
- 含有60%改性粉的薄膜具有超过7.09MPa的拉伸强度,满足市场需求并降低成本.
结论:
- 优化的加工技术显著提高了高粉含量MS/PBAT复合材料的性能.
- 这种方法使高性能,可生物降解薄膜的生产具有成本效益.
- 这项研究为生物降解聚合物在可持续包装解决方案中的应用提供了宝贵的见解.
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