作为硫电池的主体材料的酸共价有机框架
Bertha Lotsi1, Jocelyn Elgin1, Adam Karp1
1Department of Chemistry and Biochemistry, The Ohio State University, Columbus, Ohio 43210, United States.
ACS applied materials & interfaces
|September 1, 2025
概括
使用共价有机框架 (COF) 来创建硫电池 (LSB) 的宿主材料. 这种新材料有效地抑制了聚硫化物穿,显著提高了电池的性能和容量保留.
科学领域:
- 材料科学
- 电化学
- 能量储存
背景情况:
- 硫电池 (LSB) 具有高能量密度,但受到聚硫化物穿效应的影响,从而降低了性能.
- 由于其稳定性和可调性结构,共价有机框架 (COF) 是硫宿主有前途的材料.
研究的目的:
- 为LSB开发基于COF的新型宿主材料,以减轻穿效应.
- 在LSB中研究用聚硫化物链合的阴离子COF的性能.
主要方法:
- 三种含有特定有机单元 (ETMPI,TFBB,FPTZ,BPDA) 的离子COF的合成.
- 用多硫化物链对COF进行化,以产生硫宿主材料.
- 在LSB中对准备材料进行电化学测试.
主要成果:
- S@TFBB-ETMPI-COF的初始容量高达1219 mAh.
- 在0.1C的100个循环后,达到77%的优异容量保留.
- COF结构有效地抑制了穿效应,并促进了稳定的阴极电解质间相 (CEI) 层.
结论:
- 阴离子COF是有效的宿主,可以抑制LSB中的多硫化物转移.
- 开发的S@TFBB-ETMPI-COF显示了先进的储能应用的巨大潜力.
- 阴离子位点和CEI层的组合是提高LSB性能的关键.
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