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Updated: Sep 9, 2025

Morphology Control for Fully Printable Organic–Inorganic Bulk-heterojunction Solar Cells Based on a Ti-alkoxide and Semiconducting Polymer
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Morphology Control for Fully Printable Organic–Inorganic Bulk-heterojunction Solar Cells Based on a Ti-alkoxide and Semiconducting Polymer

Published on: January 10, 2017

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通过有机太阳能电池的固体添加异构化工程选择性调节捐助者和受体聚合行为,效率超过20%

Keli Shi1, Haicui Liu1, Shucheng Qin2

  • 1Key Laboratory of Solid State Optoelectronic Devices of Zhejiang Province, College of Physics and Electronic Information Engineering, Zhejiang Normal University, Jinhua, Zhejiang, 321004, China.

Angewandte Chemie (International ed. in English)
|September 1, 2025
PubMed
概括

研究人员开发了新的比索芬异构添加剂来控制有机太阳能电池 (OSC) 膜形态. 3,3-TT添加剂显著改善了分子包装和π-π堆叠,使OSC效率提高到20%以上.

关键词:
比提奥芬同位素固体添加剂形态特征有机太阳能电池光伏性能选择性监管

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Acyclic diene metathesis polymerization or ADMET polymerization involves cross-metathesis of terminal dienes, such as 1,8-nonadiene, to give linear unsaturated polymer and ethylene. As ADMET is a reversible process, the formed ethylene gas must be removed from the reaction mixture to complete the polymerization process.
Similar to cross-metathesis, ADMET also involves the formation of metallacyclobutane intermediate by [2+2] cycloaddition of one of the double bonds of a terminal diene with...
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Thermal cycloadditions are reactions where the source of activation energy needed to initiate the reaction is provided in the form of heat. A typical example of a thermally-allowed cycloaddition is the Diels–Alder reaction, which is a [4 + 2] cycloaddition. In contrast, a [2 + 2] cycloaddition is thermally forbidden.
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