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A Direct, Regioselective and Atom-Economical Synthesis of 3-Aroyl-N-hydroxy-5-nitroindoles by Cycloaddition of 4-Nitronitrosobenzene with Alkynones
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A Direct, Regioselective and Atom-Economical Synthesis of 3-Aroyl-N-hydroxy-5-nitroindoles by Cycloaddition of 4-Nitronitrosobenzene with Alkynones

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铁催化不对称的 [4+2]/Cheletropic Retro- [4+1] 循环添加与3-替代的二氧化物

Shi-Xiong Feng1, Qi-Tao Lu1, Yang Lu1

  • 1Department of Chemistry, Fudan University, 220 Handan Rd, Shanghai, 200433, China.

Angewandte Chemie (International ed. in English)
|September 2, 2025
PubMed
概括

这项研究引入了一种新型的催化不对称方法,用于使用硫二氧化物和醇合成碳循环. 新的铁催化反应产生具有高反选择性的有价值的六基.

关键词:
整热回归[4+1]循环添加德罗玛化印度类化合物反向电子需求迪尔斯阿尔德反应硫二氧化物

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