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相关概念视频

Plasticizers01:31

Plasticizers

114
Water-reducers, or plasticizers, are chemical admixtures used in concrete to improve strength and workability. These additives reduce the water-cement ratio without compromising workability, lower the cement content while maintaining the same workability, or increase workability to assist concrete placement in inaccessible areas.
Plasticizers function by using surface-active agents to create repulsive electrostatic forces between cement particles. This dispersion enhances the concrete's...
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Types of Step-Growth Polymers: Polyesters01:20

Types of Step-Growth Polymers: Polyesters

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The introduction of polyesters has brought major development to the textile industry. The wrinkle-free behavior of polyester blends has eliminated the need for starching and ironing clothes.
Polyesters are commonly prepared from terephthalic acid and ethylene glycol; the crude product is known as poly(ethylene terephthalate) or PET. However, polyesters are synthesized industrially by transesterification of dimethyl terephthalate with ethylene glycol at 150 °C. The two reactants and the...
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Superplasticizers01:30

Superplasticizers

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Superplasticizers are advanced admixtures that enhance the workability of concrete by lowering the water content without compromising the strength of the material. These substances are highly effective water reducers, improving concrete flow, making it easier to work with, and enabling concrete to reach inaccessible areas or densely reinforced sections without mechanical vibration. The key components in superplasticizers are either sulfonated melamine or naphthalene formaldehyde condensates,...
116
Polymer Classification: Stereospecificity01:26

Polymer Classification: Stereospecificity

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Polymerization generates chiral centers along the entire backbone of a polymer chain. Accordingly, the stereochemistry of the substituent group has a significant effect on polymer properties. Polymers formed from monosubstituted alkene monomers feature chiral carbons at every alternate position in the polymer backbone. Relative to the predominant orientation of substituents at the adjacent chiral carbons, the polymer can exist in three different configurations: isotactic, syndiotactic, and...
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Polymer Classification: Architecture01:14

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Polymers are classified as linear or branched on the basis of their chain architecture. The polymer chains in linear polymers have a long chain-like structure with minimal to no branching at all. Even if a polymer features large substituent groups on the monomer, which appear as branches to the skeleton, it is not considered a branched polymer. A branched polymer contains secondary polymer chains that arise from the main polymer chain. The branching occurs when the polymer growth shifts from...
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Retarders01:19

Retarders

104
Retarders are chemical admixtures designed to extend the setting time, which is especially useful when there is a delay in sequential concrete pours to prevent cold joints and to achieve a cohesive structure. Retarders, when used in appropriate amounts, can also enhance the architectural appearance of exposed aggregate finishes.
The function of retarders is to delay the setting of concrete, and this effect can be measured using a penetration test. The retardation process involves adding...
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Updated: Sep 9, 2025

Depolymerizable Olefinic Polymers Based on Fused-Ring Cyclooctene Monomers
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可分解,可回收聚氨热的可裂变添加剂

Kwangwook Ko1, David J Lundberg2, Valerie L Lensch1

  • 1Department of Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139, United States.

ACS central science
|September 2, 2025
PubMed
概括
此摘要是机器生成的。

通过使用可裂变的添加剂 (CA) 来实现化学分解的聚氨热. 本研究介绍了一个理论,并证明了选择性溶解和重聚合的低负载CA,增强了聚氨的循环性.

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科学领域:

  • 聚合物化学
  • 材料科学
  • 可持续的化学

背景情况:

  • 聚氨 (PU) 热由于永久的交叉连接而难以化学回收.
  • 现有的PU解构方法往往不切实际,需要完全替代前体.
  • 可裂变添加剂 (CA) 是一个有希望的,具有成本效益的替代品,但尚未在像PU这样的终端连接系统中得到探索.

研究的目的:

  • 开发一个可通用的理论来预测终端连接网络解构的最小CA负载.
  • 实验验证在PU热中使用基于乙烯的CA (BCS和TCJ).
  • 通过添加剂启用解构和再聚合来证明PU循环性的潜力.

主要方法:

  • 开发一个反向凝点理论来指导CA负载.
  • 将双功能可分割线 (BCS) 和三功能可分割连接 (TCJ) 纳入PU网络.
  • 选择性溶解的实验验证,材料特性调整和化学重聚.

主要成果:

  • 建立了最低 CA 负载的预测理论.
  • 低载荷 (5-12%) 的BCS和TCJ使选择性PU溶解成为可能.
  • TCJs显示出更高的解构效率,并且组合添加剂允许属性调整.
  • 在多个循环中保持机械性能的解构PU碎片的重聚.

结论:

  • 可切割的添加剂是提高聚氨热圆性的可行策略.
  • 开发的理论框架为各种端链聚合物网络的 CA 应用提供了基础.
  • 这种方法提供了可回收聚氨材料的实用途径.