使用基酸盐从片中剥离阴极材料:可行性和机制分析
Junyi Wang1, Qi Zhao1, Yixuan Wang1
1Department of Civil Engineering, The University of Hong Kong, Hong Kong, Hong Kong Special Administrative Region of China.
Waste management (New York, N.Y.)
|September 2, 2025
概括
本研究提出了一种高效的三乙烯酸盐 (TEP) 方法,用于从离子电池 (LIB) 片中剥离阴极材料. 优化过程实现了高剥离效率和TEP可重复使用性,为电池回收提供了成本效益的解决方案.
科学领域:
- 材料科学
- 化学工程
- 环境科学
背景情况:
- 电动汽车市场的增长推动了离子电池 (LIB) 的生产和浪费.
- 有效的LIB回收对于资源回收和环境保护至关重要.
- 从中去除阴极材料是一个关键但具有挑战性的回收步骤.
研究的目的:
- 开发一种简单,经济有效和高效的方法来从LIB片中剥离阴极.
- 评估三乙烯酸盐 (TEP) 作为剥离溶剂的性能和可重复使用性.
- 提供关于可持续LIB回收的剥离机制的见解.
主要方法:
- 使用三乙 (TEP) 的优化有机溶剂方法.
- 在80°C的温度下进行热处理,每分钟100转,持续20分钟.
- 机械分析以了解剥离过程.
主要成果:
- 实现了95.27%的持续剥离效率.
- 在10个溶剂循环后保持超过89%的效率,证明TEP可重复使用.
- 主要是由热溶解驱动的脱落,而不是化学降解.
结论:
- 对于工业规模的LIB阴极剥离,TEP提供了一种实用,具有成本效益和高效的解决方案.
- 开发的方法具有温和的加工条件和减少化学品的消耗.
- 这项工作促进了LIB回收的可持续预处理过程.
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