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Updated: Sep 9, 2025

Photogeneration of N-Heterocyclic Carbenes: Application in Photoinduced Ring-Opening Metathesis Polymerization
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Photogeneration of N-Heterocyclic Carbenes: Application in Photoinduced Ring-Opening Metathesis Polymerization

Published on: November 29, 2018

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通过简单的合成实现稳定的超宽吸收激素高效的NIR-II光热转换

Haozhe Zhang1, Yuhang Yang2, Jiaxing Huang1

  • 1State Key Laboratory of Luminescent Materials and Devices, Institute of Polymer Optoelectronic Materials and Devices, School of Materials Science and Engineering, South China University of Technology, Guangzhou, Guangdong, 510640, P. R. China.

Advanced science (Weinheim, Baden-Wurttemberg, Germany)
|September 3, 2025
PubMed
概括

一种新的开材料,EDOT-TPAO4,表现出极好的光热转换和太阳能驱动的水蒸发. 这种高效的有机材料为基于激素的半导体提供了一个有前途的新设计策略.

关键词:
捐赠者 接受者电子接受器开放的外光热转换一个激进的

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Photochemical Electrocyclic Reactions: Stereochemistry

The absorption of UV–visible light by conjugated systems causes the promotion of an electron from the ground state to the excited state. Consequently, photochemical electrocyclic reactions proceed via the excited-state HOMO rather than the ground-state HOMO. Since the ground- and excited-state HOMOs have different symmetries, the stereochemical outcome of electrocyclic reactions depends on the mode of activation; i.e., thermal or photochemical.
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UV–Vis Spectroscopy of Conjugated Systems

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