酸盐与富含的循环化合物的可调自组合:高能成分增强复合固体推进剂的燃烧
Zhongyu Cui1, Xin Yuan1, Yingcui Cui1
1State Key Laboratory of Space Power-Sources, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, China.
ACS applied materials & interfaces
|September 3, 2025
概括
研究人员使用自组合策略开发了新的能量化合物. 一种化合物,ATOADP,表现出高性能和稳定性,超过RDX,使其成为有前途的推进剂替代品.
科学领域:
- 能源材料研究
- 水晶工程
- 材料科学
背景情况:
- 高能度和低灵敏度对于民用和军事应用中的高能度化合物至关重要.
- 传统的合成方法往往在实现所需特性方面面临局限性.
- 晶体工程为设计具有定制特性的新能源材料提供了途径.
研究的目的:
- 探索一种以溶剂为媒介的自组合策略,用于合成能量化合物.
- 准备和描述新型氧化剂滴下能量化合物.
- 评估合成化合物的性能,稳定性和灵敏性,特别是ATOADP.
主要方法:
- 使用晶体工程和静电电位导向进行自组装.
- 使用高酸盐和富含的双循环化合物的溶剂调节自组策略.
- 合成了三种化合物:ATOADP·H2O,ATOADP和ATOAP.
- 特性包括密度,热稳定性,爆炸性能和冲击/摩擦灵敏度.
主要成果:
- 成功合成了三种新能源化合物:ATOADP·H2O,ATOADP和ATOAP.
- 与RDX相比,ATOADP具有高密度 (1.988 g cm−3),优异的热稳定性 (280.6 °C) 和优异的爆炸性能 (D = 8986 m s−1,P = 38.1 GPa).
- ATOADP显示了可接受的灵敏度 (IS = 7 J,FS = 120 N) 和稳定的燃烧.
- 将ATOADP纳入固体推进剂显著增加燃烧速度.
结论:
- 自组装策略是设计和合成高性能能量化合物的可行和有前途的方法.
- 由于其平衡性质,ATOADP是RDX在复合固体推进剂中的潜在候选物.
- 对自组装策略的进一步研究可能会导致下一代能量材料的开发.
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