准固态Li-SPAN电池的内置兼容电极电解质接口
Tao Zhang1, Zhengyuan Shen1,2, Xinhui Pan1
1Shandong Key Laboratory of Advanced Chemical Energy Storage and Intelligent Safety, Advanced Technology Research Institute, Beijing Institute of Technology, Jinan, 250300, China.
Angewandte Chemie (International ed. in English)
|September 5, 2025
概括
这项研究通过优化固体聚合物电解质和电极之间的接口来提高硫电池的性能. 一种新的现场聚合策略提高了电极/电解质兼容性,提高了电池周期寿命和稳定性.
科学领域:
- 材料科学
- 电化学
- 能量储存
背景情况:
- -硫 (Li-S) 电池提供高能量密度和低成本.
- 硫化聚烯 (SPAN) 阴极具有前景,但受到金属阳极的限制.
- 固态电解质对于提高Li-S电池的兼容性和安全性至关重要.
研究的目的:
- 开发固态硫电池的双接口优化策略.
- 增强固体聚合物电解质 (SPE) 和金属阳极/SPAN阴极之间的界面兼容性.
- 为了提高Li-S电池的电化学性能和稳定性.
主要方法:
- 在电极/SPE接口上的1,3-二氧化 (DOL) 的现场聚合.
- 在SPE中使用预埋的启动器触发聚合.
- 包含乙烯碳酸盐 (FEC) 来形成保护性介质.
主要成果:
- 显著减少了电极/电解质界面阻抗.
- 增强的界面稳定性和循环寿命 (在0. 5°C下200个循环以90%的保留率).
- 通过稳定的阴极电解质间相防止聚硫化物溶解.
结论:
- 在现场聚合的策略有效地提高了Li-S电池的界面兼容性.
- 这种方法为开发高能固态Li-S电池提供了有前途的途径.
- 优化的接口是克服当前Li-S电池技术局限性的关键.
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