揭示固态无极电池电流采集器的被动化层被忽视的作用
Yijia Wang1, Bibin Jose2, Yi Yuan1
1Department of Mechanical and Materials Engineering, University of Western Ontario, London, Ontario, N6A 5B9, Canada.
Advanced materials (Deerfield Beach, Fla.)
|September 7, 2025
概括
没有阳极的全固态金属电池从稳定的接口中受益. 由于更好的沉积和较低的电阻,铜电流采集器表现优于不钢,从而实现了更好的电池设计.
科学领域:
- 材料科学
- 电化学
- 能量储存
背景情况:
- 没有阳极的全固态金属电池 (ASSLMB) 提供高能量密度和安全性.
- 电流采集器的界面特性显著影响ASSLMB的性能.
- 表面氧化物在硫化物电解质稳定性上的作用尚未得到充分研究.
研究的目的:
- 系统地评估被动化层对无阳极ASSLMB的铜 (Cu) 和不钢 (SS) 电流采集器的影响.
- 了解硫化物电解质和Cu和SS表面氧化物之间的界面反应.
- 设计一个人工接口, 提高电池性能.
主要方法:
- 电化学阻抗光谱 (EIS) 用于评估界面电阻.
- 现场X射线吸收光谱 (XAS) 用于识别界面物种.
- 计算机建模以了解接口机制.
- 具有工程接口的电池的制造和测试.
主要成果:
- 与不钢相比,铜 (Cu) 电流采集器可以促进更稳定的沉积.
- 在循环过程中,SS表现出比Cu更高的界面阻力.
- 由于电解质-氧化物反应,和硫酸盐物种在Cu和SS接口上形成.
- 在SS上观察到过渡金属化物的部分可逆形成.
结论:
- 电流采集器上的表面氧化物对无阳极ASSLMB的界面稳定性起着至关重要的作用.
- 在没有阳极的ASSLMB中,Cu作为电流采集器表现出优越的性能.
- 工程人工接口可以显著提高涂/剥离效率,推进固体-固体接口策略.
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