离心分离色谱方法将添加剂从PVC树脂中分离出来,以支持回收过程
Noemie Auchere1, Alexandra Berlioz-Barbier1, Agnès Le Masle1
1IFP Energies nouvelles, Rond-point de l'échangeur de Solaize, BP 3, 69360 Solaize, France.
Journal of chromatography. A
|September 7, 2025
概括
离心分离染色学 (CPC) 有效地将聚合物从塑料废物中的添加剂中分离出来,有助于回收利用. 该方法允许对回收材料和污染物进行详细分析,改善化学回收策略.
科学领域:
- 聚合物科学 聚合物科学
- 分析化学 分析化学
- 可持续材料 可持续材料
背景情况:
- 塑料废物的复杂性阻碍了有效的回收利用.
- 化学回收,特别是溶解,是有前途的,但缺乏分析分离方法.
- 对回收组件的准确表征对于过程评估至关重要.
研究的目的:
- 引入离心分离色谱 (CPC) 作为分析复杂塑料矩阵的新技术.
- 为了证明CPC在将聚乙烯 (PVC) 从添加剂和污染物中分离出来的能力.
- 支持塑料先进化学回收工艺的发展.
主要方法:
- 在汉森溶解度参数的指导下,开发用于CPC的坦/DMSO/DEK双相溶剂系统.
- 使用CPC来选择性地将PVC聚合物从有机添加剂和污染物中分离出来.
- 使用NMR,FTIR和RP-LC-HRMS/MS进行分离组件的表征.
主要成果:
- CPC成功地将PVC聚合物从添加剂和污染物的混合物中分离出来.
- 该技术将添加剂分成不同的组,使其能够随后识别.
- 纯化PVC的回收量足以进行详细的光谱分析 (NMR,FTIR).
- 使用RP-LC-HRMS/MS.实现了添加物识别.
结论:
- CPC是一种强大的工具,用于分解复杂的塑料废物流.
- 这种方法有助于对回收聚合物及其相关添加剂进行全面的表征.
- CPC推动了塑料有效化学回收技术的开发和评估.
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