甲在二甲多糖制剂中形成甲:多糖结构特征的影响
Yudan Yi1, Caidan Zhang2, Qijun Li3
1College of Material and Textile Engineering, Jiaxing University, Jiaxing, 314001, China; Key Laboratory of Leather Chemistry and Engineering (Sichuan University), Ministry of Education, Chengdu, 610065, China; National Engineering Laboratory for Clean Technology of Leather Manufacture, Sichuan University, Chengdu, 610065, China.
International journal of biological macromolecules
|September 7, 2025
概括
这项研究表明,多糖体结构会影响二甲多糖体 (DAP) 中的甲形成. 选择特定的结构,如基酸盐,可以创建无甲DAP,用于可持续的皮革化.
科学领域:
- 材料科学 材料科学 材料科学
- 绿色化学 绿色化学
- 聚合物化学 聚合物化学
背景情况:
- 甲多糖 (DAP) 被用作化剂.
- 在DAP中含有甲的存在引发了环境问题.
- 优化DAP性能需要理解结构与属性之间的关系.
研究的目的:
- 调查多糖结构对DAP中甲生成的影响.
- 在DAP合成过程中识别甲形成的机制.
- 开发基于DAP的环保化剂.
主要方法:
- 通过周期性氧化合成五种二甲多糖衍生物 (DMD,DCTS,DSH,DST,DSA).
- 合成的DAP中甲含量的定量分析.
- 通过中介结构识别,阐明甲形成途径.
- 评估DAP制皮革的性能,包括收缩温度.
主要成果:
- 甲水平在DAP之间有很大的差异,DMD度最高,DSA没有甲.
- 一种涉及相邻基甲基和基/基组过氧化的机制被确定为甲的来源.
- 具有更易变的糖键的多糖化物与更高的甲含量相关.
- 用DSA皮的皮革表现出极好的热稳定性 (80.8°C的收缩温度).
结论:
- 多糖结构是DAP中甲形成的关键决定因素.
- 使用具有稳定的糖键的多糖化物,避免基甲基前体 (如酸) 消除甲.
- 没有甲的DSA为皮革制提供了可持续和高性能的替代品.
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