吸附增强的基于MOF的双联体混合矩阵膜用于CO2分离
Yurong Luo1, Jingxian Hua1, Lei Wang1
1State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, Nanjing 211816, China. panyc@njtech.edu.cn.
概括
开发了一种新的双联体金属有机框架 (MOF),Al-Fum/Asp. 这种MOF增强混合矩阵膜中的二氧化碳 (CO2) 分离,超过了2019年罗伯森上限.
科学领域:
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
- 纳米技术纳米技术
背景情况:
- 混合矩阵膜 (MMM) 对气体分离具有前景.
- 金属有机框架 (MOFs) 为增强吸附提供可调节的特性.
- 实现超出既定基准的高CO2/N2选择性仍然是一个挑战.
研究的目的:
- 为了合成一种新的双联体MOF,Al-Fum/Asp.
- 将Al-Fum/Asp纳入PIM-1以创建先进的MMM.
- 为了评估制造的MMM的CO2/N2分离性能.
主要方法:
- 合成Al-Fum/Asp通过在Al-Fum中用l-酸部分替代烟酸.
- 通过将Al-Fum/Asp纳入PIM-1矩阵来制造MMM.
- 气体透实验,以评估CO2/N2分离性能.
主要成果:
- 已经成功合成了Al-Fum/Asp MOF.
- 在Al-Fum/Asp上存在的氨基基团增强了CO2吸附.
- 结合Al-Fum/Asp的MMM表现出超过2019年罗宾逊上限的CO2/N2分离性能.
结论:
- 双联体MOF可以有效地设计用于气体分离应用.
- 阿尔-/阿斯普MOF显示了高性能二氧化碳捕获的潜力.
- 开发的MMM代表了CO2/N2分离技术的重大进步.
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